Semiconductors & Electronics

Nitride Semiconductors

Group-III and silicon nitrides spanning GaN power transistors, AlN heat spreaders, and Si3N4 photonic waveguides. Strong covalent bonding delivers wide gaps, hardness, and thermal stability.

At a glance

Class Statistics

Compounds Tracked
3,228
Multi-Source DFT
150
With Synthesis Routes
2
Avg. Agreement
0.88 / 1.00
Overview

What are Nitride Semiconductors?

Nitride semiconductors represent a critical class of wide-bandgap materials characterized by strong covalent bonding between nitrogen and group-III elements or silicon. This robust atomic structure imparts exceptional physical and electronic properties, including high breakdown fields, superior thermal conductivity, and remarkable chemical stability. Unlike traditional narrow-bandgap materials, nitrides can operate efficiently at elevated temperatures and high power densities, making them indispensable for modern electronics and optoelectronics. Gallium nitride (GaN) is perhaps the most prominent member, revolutionizing power conversion and radio-frequency applications by enabling smaller, more efficient transistors. Aluminum nitride (AlN) is highly valued for its wide bandgap and excellent thermal management capabilities, often serving as a heat spreader in high-performance packaging. Meanwhile, silicon nitride (Si3N4) has emerged as a cornerstone of integrated photonics, offering low optical loss and high refractive index contrast, which are essential for complex optical circuits and sensing technologies. The versatility of these materials stems from their ability to be engineered through alloying and heterostructure growth, allowing for the precise tuning of electronic and optical characteristics. As industries push toward higher efficiency and miniaturization, nitride semiconductors continue to be the primary enablers for next-generation power electronics, high-brightness light-emitting diodes, and advanced telecommunications infrastructure. Their inherent resistance to harsh environments further cements their role in aerospace and automotive sectors where reliability is paramount.

Members

Top Nitride Semiconductors

Ranked by data richness — literature synthesis coverage, multi-source DFT corroboration, and patent activity.

FormulaBand GapBest EAH (eV/atom)StabilityDFT SourcesRecipes
BN0.05–5.77 eV0.0000On hull (stable)40
GaN0.02–1.73 eV0.0000On hull (stable)40
InN1.15 eV0.0000On hull (stable)30
AlN3.27–4.42 eV0.0000On hull (stable)20
B2N20.05–5.77 eV0.0000On hull (stable)30
BC2N0.73–2.47 eV0.5379Above hull20
Ga2N20.02–1.73 eV0.0000On hull (stable)20
Ga36N360.02–1.73 eV0.0000On hull (stable)20
Ga32N320.02–1.73 eV0.0000On hull (stable)20
B4N40.05–5.77 eV0.0000On hull (stable)20
Al5C3N0.84–1.44 eV0.0477Metastable20
B8N80.05–5.77 eV0.0000On hull (stable)20
CaGaN1.55 eV0.0000On hull (stable)20
B3N30.05–5.77 eV0.0000On hull (stable)20
N8Si60.18–4.65 eV0.0000On hull (stable)20
Si3N40.18–4.65 eV0.0000On hull (stable)20
Al6C3N20.04–0.12 eV0.0985Metastable20
Al2N23.27–4.42 eV0.0000On hull (stable)20
BH2N5.34 eV0.0122Near hull (likely stable)20
AlGa3N42.18–2.24 eV0.0030Near hull (likely stable)30
BH6N2.70–6.11 eV0.0469Metastable20
Ga1N10.02–1.73 eV0.0000On hull (stable)10
Ga3N30.02–1.73 eV0.0000On hull (stable)10
B1N10.05–5.77 eV0.0000On hull (stable)10
Ga100N1000.02–1.73 eV0.0000On hull (stable)10
Ga150N1500.02–1.73 eV0.0000On hull (stable)10
Ga6N60.02–1.73 eV0.0000On hull (stable)10
Ga8N80.02–1.73 eV0.0000On hull (stable)10
BH4N5.73–5.95 eV0.0429Metastable10
Ba4N8Si42.92 eV0.0000On hull (stable)20
Ca16N32Si162.20–3.51 eV0.0000On hull (stable)20
N8Si4Sr42.97 eV0.0000On hull (stable)20
B32N320.05–5.77 eV0.0000On hull (stable)10
B6N60.05–5.77 eV0.0000On hull (stable)10
Si3N20.12 eV0.2510Above hull20
AlGaN22.66–2.72 eV0.0072Near hull (likely stable)20
CN2Si4.24 eV0.0354Metastable10
MgSiN23.68–4.18 eV0.0000On hull (stable)20
AlBiN21.41 eV0.2980Above hull20
AlCN5.11 eV0.3416Above hull20
Al3GaN43.35–3.41 eV0.0020Near hull (likely stable)20
In3GaN40.08 eV0.0216Near hull (likely stable)20
Mg4N8Si43.68–4.18 eV0.0000On hull (stable)20
InCN20.27 eV0.1292Above hull20
Li3BN23.10–3.45 eV0.0000On hull (stable)20
MnAlN20.12 eV0.2254Above hull20
BeSiN22.87–5.15 eV0.0000On hull (stable)20
CdSiN21.55 eV0.0329Metastable20
ScBN21.87 eV0.2565Above hull20
ScAlN23.00 eV0.1613Above hull20
Reference

Frequently Asked Questions

How many nitride semiconductors are in the database?

3,228 nitride semiconductors are tracked, of which 150 have multi-source DFT validation and 2 have documented synthesis routes.

More questions
What is the most data-rich nitride semiconductor?
BN is the most thoroughly characterized, with 301 reported structures.
Which nitride semiconductor has the widest band gap?
Among the top compounds, BH6N has the widest reported DFT band gap (6.11 eV).
Why are nitride semiconductors considered 'wide-bandgap' materials?
They are classified as wide-bandgap because the energy required to excite an electron from the valence band to the conduction band is significantly larger than in conventional semiconductors like silicon, allowing them to operate at higher voltages and temperatures.
What makes Gallium Nitride (GaN) superior for power electronics?
GaN allows for faster switching speeds and lower energy losses compared to silicon-based devices, which results in smaller, more efficient power adapters and improved performance in electric vehicle power systems.
How is Silicon Nitride (Si3N4) used in photonics?
Silicon nitride is utilized to create low-loss optical waveguides that guide light across a chip, serving as the foundation for photonic integrated circuits used in high-speed data communications and precision sensing.
Are nitride semiconductors difficult to manufacture?
While they offer superior performance, the growth of high-quality nitride crystals often requires specialized techniques like metal-organic chemical vapor deposition to manage lattice mismatches between the nitride layer and the underlying substrate.
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