Class Statistics
What are Nitride Semiconductors?
Nitride semiconductors represent a critical class of wide-bandgap materials characterized by strong covalent bonding between nitrogen and group-III elements or silicon. This robust atomic structure imparts exceptional physical and electronic properties, including high breakdown fields, superior thermal conductivity, and remarkable chemical stability. Unlike traditional narrow-bandgap materials, nitrides can operate efficiently at elevated temperatures and high power densities, making them indispensable for modern electronics and optoelectronics. Gallium nitride (GaN) is perhaps the most prominent member, revolutionizing power conversion and radio-frequency applications by enabling smaller, more efficient transistors. Aluminum nitride (AlN) is highly valued for its wide bandgap and excellent thermal management capabilities, often serving as a heat spreader in high-performance packaging. Meanwhile, silicon nitride (Si3N4) has emerged as a cornerstone of integrated photonics, offering low optical loss and high refractive index contrast, which are essential for complex optical circuits and sensing technologies. The versatility of these materials stems from their ability to be engineered through alloying and heterostructure growth, allowing for the precise tuning of electronic and optical characteristics. As industries push toward higher efficiency and miniaturization, nitride semiconductors continue to be the primary enablers for next-generation power electronics, high-brightness light-emitting diodes, and advanced telecommunications infrastructure. Their inherent resistance to harsh environments further cements their role in aerospace and automotive sectors where reliability is paramount.
Top Nitride Semiconductors
Ranked by data richness — literature synthesis coverage, multi-source DFT corroboration, and patent activity.
| Formula | Band Gap | Best EAH (eV/atom) | Stability | DFT Sources | Recipes |
|---|---|---|---|---|---|
| BN | 0.05–5.77 eV | 0.0000 | On hull (stable) | 4 | 0 |
| GaN | 0.02–1.73 eV | 0.0000 | On hull (stable) | 4 | 0 |
| InN | 1.15 eV | 0.0000 | On hull (stable) | 3 | 0 |
| AlN | 3.27–4.42 eV | 0.0000 | On hull (stable) | 2 | 0 |
| B2N2 | 0.05–5.77 eV | 0.0000 | On hull (stable) | 3 | 0 |
| BC2N | 0.73–2.47 eV | 0.5379 | Above hull | 2 | 0 |
| Ga2N2 | 0.02–1.73 eV | 0.0000 | On hull (stable) | 2 | 0 |
| Ga36N36 | 0.02–1.73 eV | 0.0000 | On hull (stable) | 2 | 0 |
| Ga32N32 | 0.02–1.73 eV | 0.0000 | On hull (stable) | 2 | 0 |
| B4N4 | 0.05–5.77 eV | 0.0000 | On hull (stable) | 2 | 0 |
| Al5C3N | 0.84–1.44 eV | 0.0477 | Metastable | 2 | 0 |
| B8N8 | 0.05–5.77 eV | 0.0000 | On hull (stable) | 2 | 0 |
| CaGaN | 1.55 eV | 0.0000 | On hull (stable) | 2 | 0 |
| B3N3 | 0.05–5.77 eV | 0.0000 | On hull (stable) | 2 | 0 |
| N8Si6 | 0.18–4.65 eV | 0.0000 | On hull (stable) | 2 | 0 |
| Si3N4 | 0.18–4.65 eV | 0.0000 | On hull (stable) | 2 | 0 |
| Al6C3N2 | 0.04–0.12 eV | 0.0985 | Metastable | 2 | 0 |
| Al2N2 | 3.27–4.42 eV | 0.0000 | On hull (stable) | 2 | 0 |
| BH2N | 5.34 eV | 0.0122 | Near hull (likely stable) | 2 | 0 |
| AlGa3N4 | 2.18–2.24 eV | 0.0030 | Near hull (likely stable) | 3 | 0 |
| BH6N | 2.70–6.11 eV | 0.0469 | Metastable | 2 | 0 |
| Ga1N1 | 0.02–1.73 eV | 0.0000 | On hull (stable) | 1 | 0 |
| Ga3N3 | 0.02–1.73 eV | 0.0000 | On hull (stable) | 1 | 0 |
| B1N1 | 0.05–5.77 eV | 0.0000 | On hull (stable) | 1 | 0 |
| Ga100N100 | 0.02–1.73 eV | 0.0000 | On hull (stable) | 1 | 0 |
| Ga150N150 | 0.02–1.73 eV | 0.0000 | On hull (stable) | 1 | 0 |
| Ga6N6 | 0.02–1.73 eV | 0.0000 | On hull (stable) | 1 | 0 |
| Ga8N8 | 0.02–1.73 eV | 0.0000 | On hull (stable) | 1 | 0 |
| BH4N | 5.73–5.95 eV | 0.0429 | Metastable | 1 | 0 |
| Ba4N8Si4 | 2.92 eV | 0.0000 | On hull (stable) | 2 | 0 |
| Ca16N32Si16 | 2.20–3.51 eV | 0.0000 | On hull (stable) | 2 | 0 |
| N8Si4Sr4 | 2.97 eV | 0.0000 | On hull (stable) | 2 | 0 |
| B32N32 | 0.05–5.77 eV | 0.0000 | On hull (stable) | 1 | 0 |
| B6N6 | 0.05–5.77 eV | 0.0000 | On hull (stable) | 1 | 0 |
| Si3N2 | 0.12 eV | 0.2510 | Above hull | 2 | 0 |
| AlGaN2 | 2.66–2.72 eV | 0.0072 | Near hull (likely stable) | 2 | 0 |
| CN2Si | 4.24 eV | 0.0354 | Metastable | 1 | 0 |
| MgSiN2 | 3.68–4.18 eV | 0.0000 | On hull (stable) | 2 | 0 |
| AlBiN2 | 1.41 eV | 0.2980 | Above hull | 2 | 0 |
| AlCN | 5.11 eV | 0.3416 | Above hull | 2 | 0 |
| Al3GaN4 | 3.35–3.41 eV | 0.0020 | Near hull (likely stable) | 2 | 0 |
| In3GaN4 | 0.08 eV | 0.0216 | Near hull (likely stable) | 2 | 0 |
| Mg4N8Si4 | 3.68–4.18 eV | 0.0000 | On hull (stable) | 2 | 0 |
| InCN2 | 0.27 eV | 0.1292 | Above hull | 2 | 0 |
| Li3BN2 | 3.10–3.45 eV | 0.0000 | On hull (stable) | 2 | 0 |
| MnAlN2 | 0.12 eV | 0.2254 | Above hull | 2 | 0 |
| BeSiN2 | 2.87–5.15 eV | 0.0000 | On hull (stable) | 2 | 0 |
| CdSiN2 | 1.55 eV | 0.0329 | Metastable | 2 | 0 |
| ScBN2 | 1.87 eV | 0.2565 | Above hull | 2 | 0 |
| ScAlN2 | 3.00 eV | 0.1613 | Above hull | 2 | 0 |
Frequently Asked Questions
How many nitride semiconductors are in the database?
3,228 nitride semiconductors are tracked, of which 150 have multi-source DFT validation and 2 have documented synthesis routes.
What is the most data-rich nitride semiconductor?
Which nitride semiconductor has the widest band gap?
Why are nitride semiconductors considered 'wide-bandgap' materials?
What makes Gallium Nitride (GaN) superior for power electronics?
How is Silicon Nitride (Si3N4) used in photonics?
Are nitride semiconductors difficult to manufacture?
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