Semiconductors & Electronics

Nitride Semiconductors

Group-III and silicon nitrides spanning GaN power transistors, AlN heat spreaders, and Si3N4 photonic waveguides. Strong covalent bonding delivers wide gaps, hardness, and thermal stability.

At a glance

Class Statistics

Compounds Tracked
2,360
Multi-Source DFT
0
With Synthesis Routes
45
Avg. Agreement
0.92 / 1.00
Overview

What are Nitride Semiconductors?

Nitride semiconductors represent a critical class of wide-bandgap materials characterized by strong covalent bonding between nitrogen and group-III elements or silicon. This robust atomic structure imparts exceptional physical and electronic properties, including high breakdown fields, superior thermal conductivity, and remarkable chemical stability. Unlike traditional narrow-bandgap materials, nitrides can operate efficiently at elevated temperatures and high power densities, making them indispensable for modern electronics and optoelectronics. Gallium nitride (GaN) is perhaps the most prominent member, revolutionizing power conversion and radio-frequency applications by enabling smaller, more efficient transistors. Aluminum nitride (AlN) is highly valued for its wide bandgap and excellent thermal management capabilities, often serving as a heat spreader in high-performance packaging. Meanwhile, silicon nitride (Si3N4) has emerged as a cornerstone of integrated photonics, offering low optical loss and high refractive index contrast, which are essential for complex optical circuits and sensing technologies. The versatility of these materials stems from their ability to be engineered through alloying and heterostructure growth, allowing for the precise tuning of electronic and optical characteristics. As industries push toward higher efficiency and miniaturization, nitride semiconductors continue to be the primary enablers for next-generation power electronics, high-brightness light-emitting diodes, and advanced telecommunications infrastructure. Their inherent resistance to harsh environments further cements their role in aerospace and automotive sectors where reliability is paramount.

Members

Top Nitride Semiconductors

Ranked by data richness — literature synthesis coverage, multi-source DFT corroboration, and patent activity.

FormulaBand GapBest EAH (eV/atom)StabilityDFT SourcesRecipes
AlN0.37–5.09 eV0.0000Stable12
GaN0.02–2.08 eV0.0000Stable11
Si3N41.43–4.84 eV0.0000Stable11
BN0.05–5.91 eV0.0000Stable10
InN0.04–1.15 eV0.0000Stable10
CaN2Si2.20–3.44 eV0.0000On hull (stable)—3
Sr2Si5N83.29–3.41 eV0.0000Stable13
CaSiN21.58–4.17 eV0.0000Unstable13
Ca2Si5N83.19–3.83 eV0.0000Stable13
B3N0.28 eV0.6195Unstable10
BC2N0.73–2.60 eV0.5091Unstable10
SiNMetallic / not reported0.6407Unstable10
Al5C3N0.84–1.69 eV0.0454Metastable10
Ca2N8Si53.34–3.65 eV0.0000On hull (stable)—3
BH6N2.70–6.39 eV0.0318Metastable10
N8Si5Sr23.20 eV0.0000On hull (stable)—3
Al6C3N20.10–0.22 eV0.0911Metastable10
CaGaN0.63–0.71 eV0.0000Stable10
BH2N4.62–5.29 eV0.1017Unstable10
AlN30.86–3.37 eV0.6622Unstable10
BN31.00 eV0.9337Unstable10
SiN25.25 eV0.3071Unstable10
N4Si30.18–4.66 eV0.0000On hull (stable)—1
Ti2AlNMetallic / not reported0.0000Stable14
BH4N5.73–6.08 eV0.0373Metastable—0
AlGaN22.67–3.08 eV0.0011Stable10
Ba2Si5N82.84–2.95 eV0.0000Stable11
LaN5Si33.10 eV0.0000On hull (stable)—2
AlInN21.20–1.63 eV0.0155Stable10
Ca6GaN50.81–0.90 eV0.0000Stable10
B6H10N5.66–5.96 eV0.0000Stable10
Si3N20.27 eV0.2825Unstable10
B3H10N5.99–6.21 eV0.0548Metastable—0
BHN44.01–4.34 eV0.1706Above hull—0
MgSiN23.62–4.46 eV0.0000Stable10
Al3GaN43.35–3.64 eV0.0000Stable10
Al2N23.26–4.07 eV—Not assessed—2
AlGa3N42.18–2.42 eV0.0030Stable10
Li3BN23.42–3.78 eV0.0000Stable10
ScBN21.81–2.21 eV0.2364Unstable10
B3H12N5.48–5.63 eV0.0641Metastable—0
BeSiN22.98–5.26 eV0.0000Stable10
B2C3N60.15–2.74 eV0.1733Unstable10
BNCl22.60–2.81 eV0.2798Unstable10
CdSiN21.74–1.89 eV0.0491Metastable10
BH8N5.62 eV0.0745Unstable10
Ca3In3N50.57–0.73 eV0.1137Unstable10
InGaN20.22–0.54 eV0.0754Metastable10
Ca3Ga2N41.91–2.25 eV0.0000Stable10
N2SiSr2.97 eV0.0000On hull (stable)—0
Reference

Frequently Asked Questions

How many nitride semiconductors are in the database?

2,360 nitride semiconductors are tracked, of which 0 have multi-source DFT validation and 45 have documented synthesis routes.

More questions
What is the most data-rich nitride semiconductor?
AlN is the most thoroughly characterized, with 703 reported structures.
Which nitride semiconductor has the widest band gap?
Among the top compounds, BH6N has the widest reported DFT band gap (6.39 eV).
Why are nitride semiconductors considered 'wide-bandgap' materials?
They are classified as wide-bandgap because the energy required to excite an electron from the valence band to the conduction band is significantly larger than in conventional semiconductors like silicon, allowing them to operate at higher voltages and temperatures.
What makes Gallium Nitride (GaN) superior for power electronics?
GaN allows for faster switching speeds and lower energy losses compared to silicon-based devices, which results in smaller, more efficient power adapters and improved performance in electric vehicle power systems.
How is Silicon Nitride (Si3N4) used in photonics?
Silicon nitride is utilized to create low-loss optical waveguides that guide light across a chip, serving as the foundation for photonic integrated circuits used in high-speed data communications and precision sensing.
Are nitride semiconductors difficult to manufacture?
While they offer superior performance, the growth of high-quality nitride crystals often requires specialized techniques like metal-organic chemical vapor deposition to manage lattice mismatches between the nitride layer and the underlying substrate.
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