Semiconductors & Electronics

Wide-Bandgap Oxide Semiconductors

Ultra-wide-gap oxides led by beta-Ga2O3 (4.8 eV), whose breakdown fields triple those of SiC. Native substrates grown from melt promise kilovolt-class power devices at silicon-like cost.

At a glance

Class Statistics

Compounds Tracked
191
Multi-Source DFT
0
With Synthesis Routes
27
Avg. Agreement
1.00 / 1.00
Overview

What are Wide-Bandgap Oxide Semiconductors?

Wide-bandgap oxide semiconductors represent a transformative class of materials characterized by exceptionally large energy gaps between their valence and conduction bands. Unlike traditional semiconductors, these oxides possess the intrinsic ability to withstand significantly higher electric fields before experiencing dielectric breakdown. This unique physical property allows for the development of power electronics that can operate at much higher voltages and temperatures than conventional silicon or even standard wide-bandgap materials like silicon carbide and gallium nitride. The chemistry of these materials typically involves metal cations bonded with oxygen, forming stable, robust crystalline lattices. Beta-gallium oxide is the most prominent member of this family, garnering intense interest due to its ability to be grown as large-area native substrates directly from the melt. This growth method is a significant advantage, as it mirrors the cost-effective production techniques used for silicon, potentially lowering the barrier to mass-market adoption. Beyond power switching, these oxides are being explored for deep-ultraviolet optoelectronics and radiation-hardened sensors. Because they can handle extreme power densities, they are essential for the next generation of energy-efficient power grids, electric vehicle drivetrains, and high-frequency communication systems. By pushing the limits of electronic performance, wide-bandgap oxides are positioning themselves as the foundational materials for future high-power, high-efficiency electronic architectures that require superior thermal stability and electrical resilience.

Members

Top Wide-Bandgap Oxide Semiconductors

Ranked by data richness — literature synthesis coverage, multi-source DFT corroboration, and patent activity.

FormulaBand GapBest EAH (eV/atom)StabilityDFT SourcesRecipes
ZnO0.14–1.25 eV0.0000Stable171
OZn0.45–1.28 eV0.0000On hull (stable)—71
O2Zn21.80–1.86 eV—Not assessed—71
O1Zn11.68–2.14 eV—Not assessed—71
In2O30.11–5.45 eV0.0000Stable112
O3Zn3Metallic / not reported—Not assessed—71
O6Zn6Metallic / not reported—Not assessed—71
O4Zn4Metallic / not reported—Not assessed—71
O8Zn8Metallic / not reported—Not assessed—71
O96Zn96Metallic / not reported—Not assessed—71
O5Zn5Metallic / not reported—Not assessed—71
SnO20.07–2.38 eV0.0000Stable19
O2Sn0.32–2.00 eV0.0000On hull (stable)—9
In16O241.12 eV—Not assessed—12
In8O120.22–0.96 eV—Not assessed—12
In4O61.17 eV—Not assessed—12
In12O181.16 eV—Not assessed—12
Ga2O30.47–2.88 eV0.0000Stable14
O4Sn20.03–0.38 eV—Not assessed—9
O8Sn40.13–0.37 eV—Not assessed—9
O16Sn80.25 eV—Not assessed—9
O24Sn120.32 eV—Not assessed—9
O2Sn1Metallic / not reported—Not assessed—9
O6Sn3Metallic / not reported—Not assessed—9
SnO0.21–1.92 eV0.0000Stable10
GaO22.95 eV0.2046Unstable10
InO20.07–0.15 eV0.2302Unstable10
GaO1.31–1.67 eV0.0000Unstable10
InO0.40–0.80 eV0.0000On hull (stable)—0
Ga2O0.68 eV0.3095Unstable10
ZnO22.38 eV0.0896Unstable10
Ga4O61.37–2.65 eV—Not assessed—4
GaO31.35 eV0.2994Above hull—0
OSn0.41–1.34 eV0.0000On hull (stable)—0
In2O0.41 eV0.2388Above hull—0
Sn2O30.67–2.18 eV0.0395Metastable—0
SnO30.70–1.75 eV0.3096Above hull—0
Zn2O0.96 eV0.7407Above hull—0
Sn3O40.58 eV0.1023Above hull—0
Sn5O61.99 eV0.0180Stable10
SnO70.63 eV0.3403Unstable10
O2Zn1.28–2.16 eV0.1355Above hull—0
Ga64O96Metallic / not reported—Not assessed—4
O4Sn30.93 eV0.2568Above hull—0
Ga4O50.35–0.68 eV0.3751Above hull—0
Sn4O110.85–1.79 eV0.2549Above hull—0
Ga4O112.05 eV0.3655Above hull—0
In4O50.21 eV0.2609Above hull—0
O6Sn51.77 eV0.0000On hull (stable)—0
O7Sn50.37 eV0.2521Above hull—0
Reference

Frequently Asked Questions

How many wide-bandgap oxide semiconductors are in the database?

191 wide-bandgap oxide semiconductors are tracked, of which 0 have multi-source DFT validation and 27 have documented synthesis routes.

More questions
What is the most data-rich wide-bandgap oxide semiconductor?
ZnO is the most thoroughly characterized, with 406 reported structures.
Which wide-bandgap oxide semiconductor has the widest band gap?
Among the top compounds, In2O3 has the widest reported DFT band gap (5.45 eV).
Why are wide-bandgap oxides considered superior to silicon for power electronics?
They possess a much higher critical breakdown field, allowing devices to block higher voltages in a smaller physical footprint while maintaining efficient operation at elevated temperatures.
What makes beta-gallium oxide particularly attractive for commercial manufacturing?
It can be synthesized using melt-growth techniques, which are scalable and cost-effective, unlike the more complex vapor-phase epitaxy required for other wide-bandgap materials.
Are there limitations to using these materials in electronic devices?
The primary challenge remains thermal management, as many of these oxides exhibit relatively low thermal conductivity compared to materials like silicon carbide, requiring advanced packaging solutions.
In what specific applications are these oxides expected to have the most impact?
They are primarily targeted for high-voltage power conversion systems, such as those found in electric vehicle charging infrastructure, renewable energy grids, and industrial motor drives.
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