Semiconductors & Electronics

III-V Semiconductors

Compound semiconductors pairing group-III metals with N, P, As, or Sb. Direct band gaps and high electron mobilities make GaN, GaAs, and InP the backbone of LEDs, RF power, and photonics.

At a glance

Class Statistics

Compounds Tracked
614
Multi-Source DFT
0
With Synthesis Routes
22
Avg. Agreement
1.00 / 1.00
Overview

What are III-V Semiconductors?

III-V semiconductors represent a critical class of compound materials formed by combining elements from group III of the periodic table, such as aluminum, gallium, or indium, with elements from group V, such as nitrogen, phosphorus, arsenic, or antimony. Unlike elemental semiconductors like silicon, these materials are characterized by their direct band gaps, which allow for efficient light emission and absorption. This fundamental property makes them indispensable in the field of optoelectronics. Furthermore, III-V materials often exhibit significantly higher electron mobility compared to silicon, enabling high-speed switching and superior performance in radio-frequency applications. The chemistry of these compounds allows for precise band gap engineering through the creation of ternary or quaternary alloys, providing researchers with the ability to tune material properties for specific wavelengths or electronic requirements. Notable members of this class include gallium nitride (GaN), which has revolutionized power electronics and blue light-emitting diodes; gallium arsenide (GaAs), a staple in high-frequency communications and satellite technology; and indium phosphide (InP), which is essential for high-speed fiber-optic telecommunications. As the demand for faster data transmission, more efficient energy conversion, and advanced sensing technologies continues to grow, III-V semiconductors remain at the forefront of material science innovation. Their ability to operate under extreme conditions and their versatility in photonic integration ensure they will continue to serve as the backbone for next-generation electronic and photonic devices, bridging the gap between traditional silicon-based electronics and the future of high-performance, light-based technologies.

Members

Top III-V Semiconductors

Ranked by data richness — literature synthesis coverage, multi-source DFT corroboration, and patent activity.

FormulaBand GapBest EAH (eV/atom)StabilityDFT SourcesRecipes
AlN0.37–5.09 eV0.0000Stable12
GaN0.02–2.08 eV0.0000Stable11
GaAs0.09–0.57 eV0.0000Stable10
InP0.33–0.73 eV0.0000Stable10
AlSb0.02–1.38 eV0.0000Stable11
GaP0.21–1.75 eV0.0000Stable10
InSb0.15–0.26 eV0.0000Stable10
AlAs0.34–1.81 eV0.0000Stable10
AlP0.73–2.16 eV0.0000Stable10
GaSb0.37 eV0.0000Stable10
InN0.04–1.15 eV0.0000Stable10
Al3P0.26 eV0.3120Unstable10
AlN30.86–3.37 eV0.6622Unstable10
InAs0.25–0.37 eV0.0000Stable10
AsGa0.19 eV0.0000On hull (stable)—0
AsIn0.02 eV0.0000On hull (stable)—0
Al2N23.26–4.07 eV—Not assessed—2
GaP50.83 eV0.0080Near hull (likely stable)—0
AlP50.30 eV0.0163Near hull (likely stable)—0
Al1N13.31–4.43 eV—Not assessed—2
Al2PMetallic / not reported0.2852Unstable10
AlAs2Metallic / not reported0.3596Unstable10
Ga2N21.07–1.93 eV—Not assessed—1
AlP2Metallic / not reported0.2079Unstable10
Al2AsMetallic / not reported0.3738Unstable10
Al3NMetallic / not reported0.6008Unstable10
AlN2Metallic / not reported0.9140Unstable10
Al4Sb41.12 eV—Not assessed—1
InSb3Metallic / not reported0.0780Unstable10
Al2SbMetallic / not reported0.3233Unstable10
Al2P21.96 eV—Not assessed—0
Al3AsMetallic / not reported0.3508Unstable10
Al3P110.14 eV0.0905Metastable—0
Ga2PMetallic / not reported0.2088Unstable10
InP3Metallic / not reported0.0000Stable10
Al1Sb11.23 eV—Not assessed—1
Ga2P21.35 eV—Not assessed—0
Al2As21.66 eV—Not assessed—0
AlP3Metallic / not reported0.2076Unstable10
GaSb3Metallic / not reported0.1896Unstable10
As2Ga20.31 eV—Not assessed—0
Ga3NMetallic / not reported0.3753Unstable10
In2P20.63 eV—Not assessed—0
Ga1N10.61–1.75 eV—Not assessed—1
Ga3SbMetallic / not reported0.1468Unstable10
GaP2Metallic / not reported0.3459Unstable10
In3SbMetallic / not reported0.0677Metastable10
InN3Metallic / not reported2.3911Above hull—0
As1Ga10.30 eV—Not assessed—0
GaAs2Metallic / not reported0.4459Unstable10
Reference

Frequently Asked Questions

How many iii-v semiconductors are in the database?

614 iii-v semiconductors are tracked, of which 0 have multi-source DFT validation and 22 have documented synthesis routes.

More questions
What is the most data-rich iii-v semiconductor?
AlN is the most thoroughly characterized, with 703 reported structures.
Which iii-v semiconductor has the widest band gap?
Among the top compounds, AlN has the widest reported DFT band gap (5.09 eV).
Why are III-V semiconductors preferred over silicon for LEDs?
III-V semiconductors typically possess a direct band gap, which allows electrons to recombine with holes to emit photons efficiently. Silicon has an indirect band gap, making it highly inefficient for light emission.
What makes III-V materials suitable for high-frequency electronics?
These materials generally exhibit high electron mobility and saturation velocity, allowing transistors to switch at much higher frequencies than those possible with conventional silicon.
Can III-V semiconductors be integrated with existing silicon technology?
Yes, through techniques like heteroepitaxy, researchers can grow thin layers of III-V materials on silicon substrates, though lattice mismatch remains a significant technical challenge to overcome.
What are the primary applications of gallium nitride (GaN)?
GaN is widely used in high-efficiency power converters, blue and ultraviolet LEDs, laser diodes, and high-power radio-frequency amplifiers for telecommunications infrastructure.
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