Semiconductors & Electronics

III-V Semiconductors

Compound semiconductors pairing group-III metals with N, P, As, or Sb. Direct band gaps and high electron mobilities make GaN, GaAs, and InP the backbone of LEDs, RF power, and photonics.

At a glance

Class Statistics

Compounds Tracked
694
Multi-Source DFT
173
With Synthesis Routes
0
Avg. Agreement
1.00 / 1.00
Overview

What are III-V Semiconductors?

III-V semiconductors represent a critical class of compound materials formed by combining elements from group III of the periodic table, such as aluminum, gallium, or indium, with elements from group V, such as nitrogen, phosphorus, arsenic, or antimony. Unlike elemental semiconductors like silicon, these materials are characterized by their direct band gaps, which allow for efficient light emission and absorption. This fundamental property makes them indispensable in the field of optoelectronics. Furthermore, III-V materials often exhibit significantly higher electron mobility compared to silicon, enabling high-speed switching and superior performance in radio-frequency applications. The chemistry of these compounds allows for precise band gap engineering through the creation of ternary or quaternary alloys, providing researchers with the ability to tune material properties for specific wavelengths or electronic requirements. Notable members of this class include gallium nitride (GaN), which has revolutionized power electronics and blue light-emitting diodes; gallium arsenide (GaAs), a staple in high-frequency communications and satellite technology; and indium phosphide (InP), which is essential for high-speed fiber-optic telecommunications. As the demand for faster data transmission, more efficient energy conversion, and advanced sensing technologies continues to grow, III-V semiconductors remain at the forefront of material science innovation. Their ability to operate under extreme conditions and their versatility in photonic integration ensure they will continue to serve as the backbone for next-generation electronic and photonic devices, bridging the gap between traditional silicon-based electronics and the future of high-performance, light-based technologies.

Members

Top III-V Semiconductors

Ranked by data richness — literature synthesis coverage, multi-source DFT corroboration, and patent activity.

FormulaBand GapBest EAH (eV/atom)StabilityDFT SourcesRecipes
AlAs1.19–1.69 eV0.0000On hull (stable)40
AlSb0.78–1.23 eV0.0000On hull (stable)40
GaN0.02–1.73 eV0.0000On hull (stable)40
InN1.15 eV0.0000On hull (stable)30
InP0.45–0.53 eV0.0000On hull (stable)30
AlN3.27–4.42 eV0.0000On hull (stable)20
AlP1.63–2.39 eV0.0000On hull (stable)20
GaP0.21–1.60 eV0.0000On hull (stable)20
Al2P21.63–2.39 eV0.0000On hull (stable)30
Al2As21.19–1.69 eV0.0000On hull (stable)30
Al2Sb20.78–1.23 eV0.0000On hull (stable)30
As2In20.57 eV0.0000On hull (stable)30
As3In30.57 eV0.0000On hull (stable)30
Ga2N20.02–1.73 eV0.0000On hull (stable)20
Ga36N360.02–1.73 eV0.0000On hull (stable)20
GaAs0.22 eV0.0000On hull (stable)20
InAs0.57 eV0.0000On hull (stable)20
InSbMetallic / not reported0.0000On hull (stable)40
Al3Sb30.78–1.23 eV0.0000On hull (stable)30
Ga32N320.02–1.73 eV0.0000On hull (stable)20
As2Ga20.22 eV0.0000On hull (stable)20
Al4P41.63–2.82 eV0.0000On hull (stable)30
Al4Sb40.78–1.23 eV0.0000On hull (stable)30
Ga2P20.21–1.60 eV0.0000On hull (stable)20
In2P20.45–0.53 eV0.0000On hull (stable)20
Al2N23.27–4.42 eV0.0000On hull (stable)20
As8Ga80.22 eV0.0000On hull (stable)20
As3Ga30.22 eV0.0000On hull (stable)20
As4Ga40.19–0.54 eV0.0000On hull (stable)20
Al3As31.19–1.69 eV0.0000On hull (stable)20
As1Ga10.22 eV0.0000On hull (stable)10
Ga1N10.02–1.73 eV0.0000On hull (stable)10
Ga3N30.02–1.73 eV0.0000On hull (stable)10
AsGa0.22 eV0.0000On hull (stable)10
Ga100N1000.02–1.73 eV0.0000On hull (stable)10
Ga150N1500.02–1.73 eV0.0000On hull (stable)10
Ga3P30.21–1.60 eV0.0000On hull (stable)20
Ga6N60.02–1.73 eV0.0000On hull (stable)10
Ga8N80.02–1.73 eV0.0000On hull (stable)10
Al8Sb80.78–1.23 eV0.0000On hull (stable)20
In4P40.43–0.69 eV0.0000On hull (stable)20
Ga4P40.21–1.67 eV0.0000On hull (stable)20
Al6As61.19–1.69 eV0.0000On hull (stable)20
As8In80.57 eV0.0000On hull (stable)20
In3P30.45–0.53 eV0.0000On hull (stable)20
Al3P31.63–2.39 eV0.0000On hull (stable)20
As6In60.57 eV0.0000On hull (stable)20
Al32As321.19–1.69 eV0.0000On hull (stable)20
Al6P61.63–2.39 eV0.0000On hull (stable)20
Al6Sb60.78–1.23 eV0.0000On hull (stable)20
Reference

Frequently Asked Questions

How many iii-v semiconductors are in the database?

694 iii-v semiconductors are tracked, of which 173 have multi-source DFT validation and 0 have documented synthesis routes.

More questions
What is the most data-rich iii-v semiconductor?
AlAs is the most thoroughly characterized, with 96 reported structures.
Which iii-v semiconductor has the widest band gap?
Among the top compounds, AlN has the widest reported DFT band gap (4.42 eV).
Why are III-V semiconductors preferred over silicon for LEDs?
III-V semiconductors typically possess a direct band gap, which allows electrons to recombine with holes to emit photons efficiently. Silicon has an indirect band gap, making it highly inefficient for light emission.
What makes III-V materials suitable for high-frequency electronics?
These materials generally exhibit high electron mobility and saturation velocity, allowing transistors to switch at much higher frequencies than those possible with conventional silicon.
Can III-V semiconductors be integrated with existing silicon technology?
Yes, through techniques like heteroepitaxy, researchers can grow thin layers of III-V materials on silicon substrates, though lattice mismatch remains a significant technical challenge to overcome.
What are the primary applications of gallium nitride (GaN)?
GaN is widely used in high-efficiency power converters, blue and ultraviolet LEDs, laser diodes, and high-power radio-frequency amplifiers for telecommunications infrastructure.
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