SnO
tin(II) oxide · stannous oxide
SnO is a thermodynamically stable semiconducting oxide used primarily as a high-capacity anode material in advanced battery research.

About tin(II) oxide
SnO is a semiconducting binary oxide that occupies a stable position on the thermodynamic convex hull. As a member of the conversion oxide anode class, it is highly valued for its ability to facilitate high-capacity electrochemical reactions through the reversible formation and decomposition of metallic tin phases.
This material is a subject of extensive research due to its significant structural diversity, with hundreds of reported configurations across major databases. Its electronic nature and structural stability make it a compelling candidate for advanced battery technologies seeking to surpass the limitations of conventional intercalation materials.
Key Properties
Cross-validated computational properties for tin(II) oxide, aggregated across 4 databases.
Band GapEnergy needed to move an electron from the valence band to the conduction band. Lower or zero values tend to behave more metallic; larger gaps are more insulating or semiconducting.
Energy Above HullThermodynamic distance from the most stable set of competing phases. 0 eV/atom is on the convex hull; small positive values may still be experimentally accessible.
StabilityA plain-language summary of the best reported energy-above-hull result. It reflects whether the lowest-energy structure is on, near, or far from the stability hull.
StructuresCount of reported calculated crystal structures for this formula, including alternate polymorphs, source databases, and observed space groups.
Synthesis Routes
Literature-extracted synthesis procedures targeting SnO.
Applications
Where tin(II) oxide is used.
Patent Landscape
9 patents reference SnO or close compositional variants.
| Patent | Title | Assignee | Granted |
|---|---|---|---|
| 8603418 | Process for making SnO | — | — |
| 8974752 | Process for treating crusty SnO | — | — |
| 8501293 | Plurality of SnO flakes | — | — |
| 4695330 | Method of manufacturing internal oxidized Ag-SnO system alloy contact materials | — | — |
| 5102480 | Ag-SnO-CdO electrical contact materials and manufacturing method thereof | — | — |
| 4647322 | Internal oxidized Ag-SnO system alloy electrical contact materials | — | — |
| 4680162 | Method for preparing Ag-SnO system alloy electrical contact material | — | — |
| 4243413 | Integrated Ag-SnO alloy electrical contact materials | — | — |
| 5078810 | Method of making Ag-SnO contact materials by high pressure internal oxidation | — | — |
Frequently Asked Questions
Common questions about tin(II) oxide, answered from cross-validated data.
What is SnO?
SnO is a thermodynamically stable semiconducting oxide used primarily as a high-capacity anode material in advanced battery research.
What is SnO used for?
What is the band gap of SnO?
Is SnO a metal, semiconductor, or insulator?
Is SnO thermodynamically stable?
How many polymorphs of SnO are known?
How is SnO synthesized?
What elements does SnO contain?
Where does the data for SnO come from?
How It Compares
Within the conversion oxide anodes class.
Within the family of conversion oxide anodes, SnO offers a distinct electrochemical profile compared to siblings like SnO2. While both are tin-based, SnO provides a different pathway for lithiation, and it stands out among transition metal oxides like CuO or Fe2O3 by leveraging the unique alloying chemistry of tin to achieve high theoretical capacities.
Related Compounds
Other Conversion Oxide Anodes in the database.
Data sources & attribution
- latticegraph — Lattice Graph Materials Intelligence Platform
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