Co3O4

Cobalt(II,III) oxide · Cobaltosic oxide, Cobalt black

Co3O4 is a stable, metallic transition metal oxide used primarily as a high-capacity anode material in advanced electrochemical energy storage devices.

Crystal structure of Co3O4
Ground-state structure · Materials Project
Overview

About Cobalt(II,III) oxide

Co3O4 is a prominent conversion oxide anode material characterized by its metallic electronic nature and robust thermodynamic stability. As a member of the spinel-structured oxides, it is highly valued for its ability to facilitate high-capacity electrochemical reactions through conversion mechanisms during charge and discharge cycles.

This compound is widely utilized in the development of next-generation lithium-ion batteries and supercapacitors. Its structural reliability and favorable electrochemical kinetics make it a subject of extensive research for improving energy density and cycle life in portable electronics and electric vehicle power sources.

At a glance

Key Properties

Cross-validated computational properties for Cobalt(II,III) oxide, aggregated across 5 databases.

Band Gap

Metallic / not reported

Energy Above Hull

0.000 eV/atom
Best (lowest) across sources

Stability

On hull (stable)
4 DFT sources

Structures

30
5 databases, 9 space groups
Synthesis

Synthesis Routes

Literature-extracted synthesis procedures targeting Co3O4.

Sol Gel
Procedure available · ceder_sol_gel
Sol Gel
Procedure available · ceder_sol_gel
Sol Gel
Procedure available · ceder_sol_gel
Sol Gel
Procedure available · ceder_sol_gel
Solid State
Procedure available · ceder_solid_state
Uses

Applications

Where Cobalt(II,III) oxide is used.

Lithium-ion battery anodesSupercapacitor electrodesGas sensorsCatalysisPigments
Intellectual Property

Patent Landscape

7 patents reference Co3O4 or close compositional variants.

PatentTitleAssigneeGranted
12358810Co3O4/CuO/MgO and (Cu0.97Co0.03)O/MgO/CoO Nanocomposites and method of pechini sol-gel fabricating
10581062Nanocubic Co3O4/few-layer graphene composites and related anode components
11005109Electrochemical cell including cathode with main phase of perovskite oxide and second phase of Co3O4 and (Co,F
10987659Synthesis of TiO2/Co3O4 core-shell photocatalysts
10533258Method of making Co3O4 nanorods for electrocatalytic water splitting
11465913Porous Co3O4 nanoparticles and method for preparing the same
9074296Mesoporous Co3O4 nanoparticles, associated methods and applications
Reference

Frequently Asked Questions

Common questions about Cobalt(II,III) oxide, answered from cross-validated data.

What is Co3O4?

Co3O4 is a stable, metallic transition metal oxide used primarily as a high-capacity anode material in advanced electrochemical energy storage devices.

More questions
What is Co3O4 used for?
Cobalt(II,III) oxide (Co3O4) is used in lithium-ion battery anodes, supercapacitor electrodes, gas sensors, catalysis, and pigments.
What is the band gap of Co3O4?
Cobalt(II,III) oxide (Co3O4) is computed to be metallic (no band gap) in the reported DFT structures.
Is Co3O4 a metal, semiconductor, or insulator?
Computed band structures report no gap, so it is metallic.
Is Co3O4 thermodynamically stable?
Yes — Cobalt(II,III) oxide (Co3O4) sits on the convex hull (energy above hull 0 eV/atom), i.e. on hull (stable).
How many polymorphs of Co3O4 are known?
30 structures of Co3O4 are reported across 5 databases, spanning 9 distinct space groups.
How is Co3O4 synthesized?
Literature-reported routes for Co3O4 include sol gel, solid state (5 procedures documented).
What elements does Co3O4 contain?
Cobalt(II,III) oxide (Co3O4) contains Co and O (2 elements).
Where does the data for Co3O4 come from?
Co3O4 data is cross-referenced from latticegraph.
Comparison

How It Compares

Within the conversion oxide anodes class.

Within the family of conversion oxide anodes, Co3O4 stands out for its exceptional structural stability compared to more volatile counterparts like MnO2. While it shares a similar conversion mechanism with Fe3O4 and CuO, Co3O4 is often favored for its superior electronic conductivity, which mitigates some of the kinetic limitations typically associated with transition metal oxide electrodes.

Explore

Related Compounds

Other Conversion Oxide Anodes in the database.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

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