Spinel Lithium Manganese Oxides
Three-dimensional spinel frameworks such as LiMn2O4 and the high-voltage LiNi0.5Mn1.5O4, offering fast Li-ion diffusion and low-cost manganese chemistry for power-oriented cells.
Class Statistics
Top Spinel Lithium Manganese Oxides
Ranked by data richness — literature synthesis coverage, multi-source DFT corroboration, and patent activity.
| Formula | Band Gap | Best EAH (eV/atom) | Stability | DFT Sources | Recipes |
|---|---|---|---|---|---|
| LiMn2O4 | 0.02–1.22 eV | 0.0000 | Stable | 1 | 386 |
| LiMnO2 | 0.02–1.99 eV | 0.0000 | Stable | 1 | 23 |
| Li2MnO3 | 0.61–2.08 eV | 0.0000 | Stable | 1 | 57 |
| Li2Mn3NiO8 | 0.28–1.85 eV | 0.0000 | Stable | 1 | 171 |
| Li2MnNiO4 | 0.30 eV | 0.0308 | Metastable | 1 | 27 |
| Li2Mn2O4 | 0.46–0.94 eV | — | Not assessed | — | 23 |
| Li4Mn2O6 | 1.80 eV | — | Not assessed | — | 57 |
| Li4Mn4O8 | 1.22 eV | — | Not assessed | — | 23 |
| Li8Mn4O12 | 1.80 eV | — | Not assessed | — | 57 |
| Li2MnSiO4 | 1.89–3.36 eV | 0.0000 | Stable | 1 | 15 |
| Li4Mn5O12 | 1.00–1.22 eV | 0.0000 | On hull (stable) | — | 16 |
| Li2Mn3FeO8 | 0.05 eV | 0.0000 | Stable | 1 | 15 |
| Li2Mn4O8 | Metallic / not reported | — | Not assessed | — | 386 |
| Li2MnO4Si | 1.96–3.07 eV | 0.0000 | On hull (stable) | — | 15 |
| Li0.5Mn0.5O | Metallic / not reported | — | Not assessed | — | 23 |
| LiMn0.5Ni0.5O2 | Metallic / not reported | — | Not assessed | — | 27 |
| LiMn1.5Ni0.5O4 | Metallic / not reported | — | Not assessed | — | 171 |
| FeLi2Mn3O8 | 0.01–0.87 eV | 0.0073 | Near hull (likely stable) | — | 15 |
| Li2Mn3CoO8 | 0.07 eV | 0.0086 | Stable | 1 | 12 |
| Li4Mn2O8Si2 | 3.07 eV | — | Not assessed | — | 15 |
| CoLi2Mn3O8 | 0.25–1.37 eV | 0.0000 | On hull (stable) | — | 12 |
| LiMnCoO4 | 0.29–1.56 eV | 0.0000 | Stable | 1 | 9 |
| CoLiMnO4 | 0.25 eV | 0.0294 | Metastable | — | 9 |
| LiMnBO3 | 1.47–3.01 eV | 0.0000 | Metastable | 1 | 6 |
| Li2Mn4O9 | 0.25 eV | 0.0829 | Metastable | — | 8 |
| BLiMnO3 | 1.97–2.93 eV | 0.0007 | On hull (stable) | — | 6 |
| Li3MnCoO5 | 0.01–0.77 eV | 0.0000 | Stable | 1 | 4 |
| Li2Mn3O8Ti | 0.73–0.96 eV | 0.0154 | Near hull (likely stable) | — | 6 |
| CoLi3MnO5 | 0.01–1.73 eV | 0.0491 | Metastable | — | 4 |
| LiMnO4Ti | 0.02–1.52 eV | 0.0196 | Near hull (likely stable) | — | 5 |
| Li2MnO2 | 0.35–2.92 eV | 0.0041 | Metastable | 1 | 3 |
| Cr2Li5Mn3O10 | 0.91 eV | 0.0359 | Metastable | — | 5 |
| B3Li3Mn3O9 | 2.58 eV | — | Not assessed | — | 6 |
| FeLiMnO4 | 0.62–1.43 eV | 0.0073 | Near hull (likely stable) | — | 4 |
| Li2MnO8Sn3 | 1.19 eV | 0.0459 | Metastable | — | 4 |
| Li5Mn3O8 | 0.20–1.18 eV | 0.0000 | Stable | 1 | 0 |
| LiTiMnO4 | Metallic / not reported | 0.0385 | Metastable | 1 | 5 |
| Li5Mn3Cr2O10 | Metallic / not reported | 0.0238 | Stable | 1 | 5 |
| Li2MgMn3O8 | 0.73–1.99 eV | 0.0000 | Stable | 1 | 1 |
| Li5Mn7O16 | 0.78 eV | 0.0000 | On hull (stable) | — | 3 |
| LiMnVO4 | 0.15–2.20 eV | 0.0000 | Stable | 1 | 1 |
| Li4Mn3O7 | 0.30–1.26 eV | 0.0005 | Stable | 1 | 0 |
| Li7Mn5O12 | 0.07–1.29 eV | 0.0000 | Stable | 1 | 0 |
| Li3MnO4 | Metallic / not reported | 0.0087 | Stable | 1 | 4 |
| Li3Mn4O8 | 0.25–0.74 eV | 0.0266 | Metastable | 1 | 0 |
| Li4Mn3CoO8 | 0.05–0.37 eV | 0.0629 | Metastable | 1 | 0 |
| Li7Mn4CoO12 | 0.02–0.20 eV | 0.0127 | Stable | 1 | 0 |
| Li4Mn3NbO8 | 0.02–0.97 eV | 0.0744 | Metastable | 1 | 0 |
| LiMnFeO4 | Metallic / not reported | 0.0262 | Metastable | 1 | 4 |
| Li3Mn2O5 | 0.12–1.41 eV | 0.0000 | Stable | 1 | 0 |
Frequently Asked Questions
How many spinel lithium manganese oxides are in the database?
1,417 spinel lithium manganese oxides are tracked, of which 0 have multi-source DFT validation and 83 have documented synthesis routes.
What is the most data-rich spinel lithium manganese oxide?
Which spinel lithium manganese oxide has the widest band gap?
Why are spinel manganese oxides preferred for power-oriented applications?
What is the primary advantage of using manganese in these cathode materials?
What is the role of nickel substitution in LiNi0.5Mn1.5O4?
What is the main drawback associated with the cycling of spinel manganese oxides?
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Related Material Classes
Screen spinel lithium manganese oxides computationally
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