Li2MnO2

Li2MnO2 is a metastable, semiconducting layered oxide containing lithium and manganese that is primarily investigated for its potential in electrochemical energy storage.

Crystal structure of Li2MnO2
Ground-state structure · Materials Project
Overview

About Li2MnO2

Li2MnO2 belongs to the class of layered lithium transition-metal oxides, characterized by its semiconducting electronic nature. As a metastable compound, it represents a complex phase within the lithium-manganese-oxygen system, offering unique structural configurations for ion transport studies.

This material is of significant interest in materials science research, particularly for its role in the development of next-generation energy storage systems. Its structural properties are closely monitored to understand how metastable phases can be leveraged to improve electrochemical performance in lithium-based devices.

At a glance

Key Properties

Cross-validated computational properties for Li2MnO2, aggregated across 3 databases.

Band Gap

2.43 eV
Range across DFT structures

Energy Above Hull

0.028 eV/atom
Best (lowest) across sources

Stability

Metastable
2 DFT sources

Structures

10
3 databases, 3 space groups
Synthesis

Synthesis Routes

Literature-extracted synthesis procedures targeting Li2MnO2.

Sol Gel
Procedure available · ceder_sol_gel
Sol Gel
Procedure available · ceder_sol_gel
Sol Gel
Procedure available · ceder_sol_gel
Uses

Applications

Where Li2MnO2 is used.

Lithium-ion battery researchElectrochemical energy storage development
Reference

Frequently Asked Questions

Common questions about Li2MnO2, answered from cross-validated data.

What is Li2MnO2?

Li2MnO2 is a metastable, semiconducting layered oxide containing lithium and manganese that is primarily investigated for its potential in electrochemical energy storage.

More questions
What is Li2MnO2 used for?
Li2MnO2 is used in lithium-ion battery research and electrochemical energy storage development.
What is the band gap of Li2MnO2?
Li2MnO2 has a DFT-computed band gap of 2.43 eV across 10 reported structures.
Is Li2MnO2 a metal, semiconductor, or insulator?
With a band gap up to 2.43 eV it is a semiconductor.
Is Li2MnO2 thermodynamically stable?
Li2MnO2 has a lowest energy above hull of 0.028 eV/atom (metastable).
How many polymorphs of Li2MnO2 are known?
10 structures of Li2MnO2 are reported across 3 databases, spanning 3 distinct space groups.
How is Li2MnO2 synthesized?
Literature-reported routes for Li2MnO2 include sol gel (3 procedures documented).
What elements does Li2MnO2 contain?
Li2MnO2 contains Li, Mn, and O (3 elements).
Where does the data for Li2MnO2 come from?
Li2MnO2 data is cross-referenced from latticegraph.
Comparison

How It Compares

Within the layered lithium transition-metal oxides class.

Within the diverse family of layered lithium transition-metal oxides, Li2MnO2 occupies a distinct niche compared to more conventional materials like LiCoO2 or LiNiO2. While many of its siblings are highly stable and widely utilized in commercial cathodes, Li2MnO2 is notable for its metastable character, which contrasts with the more thermodynamically robust structures found elsewhere in the class.

Explore

Related Compounds

Other Layered Lithium Transition-Metal Oxides in the database.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

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