AlBiO3

AlBiO3 is a metastable, wide-gap insulating oxide that serves as a specialized catalyst in materials research.

Crystal structure of AlBiO3
Ground-state structure · Materials Project
Overview

About AlBiO3

AlBiO3 is a complex oxide belonging to the spinel-related family, characterized by its wide-gap insulating electronic nature. As a metastable phase, it represents a unique structural arrangement that offers distinct catalytic pathways compared to more conventional, highly stable oxide materials. Its synthesis and characterization are subjects of ongoing interest in materials science due to the specific coordination environments provided by the aluminum and bismuth cations.

This compound is primarily investigated for its role in specialized catalytic processes where precise electronic control is required. Because of its metastable status, it is often explored in experimental settings to understand how structural defects and non-equilibrium states influence catalytic activity, making it a specialized candidate for research into novel chemical transformations.

At a glance

Key Properties

Cross-validated computational properties for AlBiO3, aggregated across 3 databases.

Band Gap

0.19–3.00 eV
Range across DFT structures

Energy Above Hull

0.053 eV/atom
Best (lowest) across sources

Stability

Metastable
2 DFT sources

Structures

25
3 databases, 8 space groups
Synthesis

Synthesis Routes

Literature-extracted synthesis procedures targeting AlBiO3.

Sol Gel
Procedure available · ceder_sol_gel
Uses

Applications

Where AlBiO3 is used.

Advanced chemical catalysisMaterials science researchOxidation reaction studies
Reference

Frequently Asked Questions

Common questions about AlBiO3, answered from cross-validated data.

What is AlBiO3?

AlBiO3 is a metastable, wide-gap insulating oxide that serves as a specialized catalyst in materials research.

More questions
What is AlBiO3 used for?
AlBiO3 is used in advanced chemical catalysis, materials science research, and oxidation reaction studies.
What is the band gap of AlBiO3?
AlBiO3 has a DFT-computed band gap of 0.19–3.00 eV across 25 reported structures.
Is AlBiO3 a metal, semiconductor, or insulator?
With a wide band gap up to 3.00 eV it is an insulator / wide-band-gap material.
Is AlBiO3 thermodynamically stable?
AlBiO3 has a lowest energy above hull of 0.053 eV/atom (metastable).
How many polymorphs of AlBiO3 are known?
25 structures of AlBiO3 are reported across 3 databases, spanning 8 distinct space groups.
How is AlBiO3 synthesized?
Literature-reported routes for AlBiO3 include sol gel.
What elements does AlBiO3 contain?
AlBiO3 contains Al, Bi, and O (3 elements).
Where does the data for AlBiO3 come from?
AlBiO3 data is cross-referenced from latticegraph.
Comparison

How It Compares

Within the spinel oxide catalysts class.

Unlike the highly stable and widely utilized MgAl2O4 or the robust binary oxides like ZnO and NiO, AlBiO3 occupies a more precarious thermodynamic position. While LaAlO3 and other perovskite-structured aluminates are frequently employed for their structural rigidity, AlBiO3 offers a different structural motif that allows for unique surface reactivity, distinguishing it from the more common, thermodynamically favored members of the spinel and perovskite oxide classes.

Explore

Related Compounds

Other Spinel Oxide Catalysts in the database.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

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