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PGM-Free Catalysts Near the Sabatier Optimum

A curated catalyst screen for non-PGM HER candidates that should be evaluated by binding-energy distance, evidence count, synthesis route, and supply risk.

Search intent
Find PGM-free HER catalysts that are plausibly close to the Sabatier activity peak.
Inclusion rules
  • No Pt, Pd, Ir, Ru, Rh, or Os
  • HER-relevant surface or literature role
  • Evidence suitable for follow-up electrochemical validation
Indexing posture
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Ranked list

Candidate Materials

CandidateRoleStabilitySynthesisPatent DensitySupply RiskWhy It Matters
Cu3SbS4Sulfide HER candidateMedium to highMediumLow to mediumMediumGood example of a non-obvious PGM-free sulfide candidate.
Evidence: Catalyst screen plus sulfide literature
Ni3PPhosphide benchmarkHighHighMediumMediumPractical non-PGM baseline for phosphide screens.
Evidence: HER phosphide literature
MoS2Layered chalcogenide benchmarkHighHighHighMediumCanonical edge-site comparator for PGM-free designs.
Evidence: Chalcogenide HER literature
FeS2Low-cost sulfide comparatorHighHighLow to mediumLowUseful low-cost floor for candidate triage.
Evidence: Pyrite and sulfide catalyst literature
Related screens

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