Superconductors

A15 Superconductors

Cr3Si-structure intermetallics including Nb3Sn, the workhorse of high-field superconducting magnets from MRI to ITER, carrying supercurrent at fields where NbTi fails.

At a glance

Class Statistics

Compounds Tracked
670
Multi-Source DFT
110
With Synthesis Routes
0
Avg. Agreement
0.57 / 1.00
Overview

What are A15 Superconductors?

A15 superconductors represent a critical class of intermetallic compounds characterized by the A3B stoichiometry, where A typically denotes a transition metal such as niobium or vanadium, and B represents a non-transition element like tin, aluminum, or silicon. These materials crystallize in the A15 cubic structure, which features orthogonal chains of transition metal atoms running through the lattice. This unique atomic arrangement is fundamental to their high superconducting performance, as it facilitates a high density of states at the Fermi level, contributing to elevated transition temperatures and robust upper critical fields. Among this group, niobium-tin (Nb3Sn) stands out as the preeminent industrial material, serving as the workhorse for high-field superconducting magnets. Unlike conventional niobium-titanium alloys, which reach their operational limits in high-magnetic-field environments, A15 compounds maintain their superconducting state under significantly more intense magnetic flux. This capability makes them indispensable for advanced technological applications, including the powerful magnets required for magnetic resonance imaging (MRI) systems and the massive fusion reactors like ITER. While these materials are inherently brittle, necessitating sophisticated manufacturing techniques such as the bronze-process or internal-tin-process to form multifilamentary wires, their role in enabling high-field physics remains unmatched. Ongoing research continues to explore ways to enhance their strain tolerance and current-carrying capacity, ensuring that A15 superconductors remain central to the future of high-energy particle accelerators and large-scale energy infrastructure.

Members

Top A15 Superconductors

Ranked by data richness — literature synthesis coverage, multi-source DFT corroboration, and patent activity.

FormulaBand GapBest EAH (eV/atom)StabilityDFT SourcesRecipes
NbSn2Metallic / not reported0.0000On hull (stable)30
AlVMetallic / not reported0.0000On hull (stable)20
Nb3SiMetallic / not reported0.0129Near hull (likely stable)20
AlV3Metallic / not reported0.0000On hull (stable)30
Nb5Si3Metallic / not reported0.0000On hull (stable)30
VGaMetallic / not reported0.0908Metastable20
Al3VMetallic / not reported0.0000On hull (stable)30
AlV2Metallic / not reported0.0250Metastable20
Nb2AlMetallic / not reported0.0000On hull (stable)20
Nb3SnMetallic / not reported0.0000On hull (stable)20
NbGe2Metallic / not reported0.0000On hull (stable)20
NbSi2Metallic / not reported0.0000On hull (stable)20
V3SiMetallic / not reported0.0000On hull (stable)20
VGe2Metallic / not reported0.0326Metastable20
VSi2Metallic / not reported0.0000On hull (stable)20
Nb3GeMetallic / not reported0.0019Near hull (likely stable)20
Nb3Si2Metallic / not reported0.0193Near hull (likely stable)20
VSn2Metallic / not reported0.0266Metastable20
V3SnMetallic / not reported0.0000On hull (stable)20
NbAl3Metallic / not reported0.0000On hull (stable)20
NbGa3Metallic / not reported0.0000On hull (stable)20
Nb3AlMetallic / not reported0.0409Metastable20
NbSiMetallic / not reportedNot assessed20
NbSnMetallic / not reportedNot assessed20
Nb3Ga2Metallic / not reported0.0000On hull (stable)20
Nb6Si2Metallic / not reported0.0129Near hull (likely stable)20
V3GeMetallic / not reported0.0000On hull (stable)20
Nb5Ge3Metallic / not reported0.0000On hull (stable)20
Si4V2Metallic / not reported0.0000On hull (stable)20
Nb12Si4Metallic / not reported0.0129Near hull (likely stable)20
Nb2Sn4Metallic / not reported0.0000On hull (stable)20
Nb3GaMetallic / not reported0.0584Metastable20
Sn8V4Metallic / not reported0.0266Metastable20
Ga6V6Metallic / not reported0.0908Metastable20
GaVMetallic / not reported0.0908Metastable10
V3Ga2Metallic / not reported0.0911Metastable20
V5Si3Metallic / not reported0.0000On hull (stable)20
VGe3Metallic / not reported0.3679Above hull20
Al6V6Metallic / not reported0.0000On hull (stable)20
Ge4V2Metallic / not reported0.0326Metastable20
Nb3Si6Metallic / not reported0.0000On hull (stable)20
Nb3Sn6Metallic / not reported0.0000On hull (stable)20
V3GaMetallic / not reported0.0000On hull (stable)20
V5Ge3Metallic / not reported0.0000On hull (stable)20
Si2V6Metallic / not reported0.0000On hull (stable)10
Nb3Si1Metallic / not reported0.0129Near hull (likely stable)10
Al10Nb20Metallic / not reported0.0000On hull (stable)20
Al8V5Metallic / not reported0.0524Metastable20
Si8V4Metallic / not reported0.0000On hull (stable)20
Nb4AlMetallic / not reported0.1045Above hull20
Reference

Frequently Asked Questions

How many a15 superconductors are in the database?
670 a15 superconductors are tracked, of which 110 have multi-source DFT validation and 0 have documented synthesis routes.
What is the most data-rich a15 superconductor?
NbSn2 is the most thoroughly characterized, with 69 reported structures.
Why are A15 superconductors considered brittle?
A15 compounds are intermetallic phases with complex crystal structures that lack the ductility found in metallic solid solutions, making them susceptible to fracture under mechanical strain.
How does Nb3Sn compare to NbTi in magnetic applications?
Nb3Sn can operate at significantly higher magnetic field strengths than NbTi, allowing for the creation of more powerful magnets in applications where NbTi would lose its superconductivity.
What is the significance of the A15 crystal structure?
The structure features orthogonal chains of transition metal atoms that create a high density of electronic states, which is essential for achieving high superconducting transition temperatures.
Are A15 superconductors used in commercial technology?
Yes, they are widely utilized in high-field magnets for medical MRI machines and are critical components in the development of large-scale fusion energy research facilities.
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