Superconductors

A15 Superconductors

Cr3Si-structure intermetallics including Nb3Sn, the workhorse of high-field superconducting magnets from MRI to ITER, carrying supercurrent at fields where NbTi fails.

At a glance

Class Statistics

Compounds Tracked
682
Multi-Source DFT
0
With Synthesis Routes
12
Avg. Agreement
0.63 / 1.00
Overview

What are A15 Superconductors?

A15 superconductors represent a critical class of intermetallic compounds characterized by the A3B stoichiometry, where A typically denotes a transition metal such as niobium or vanadium, and B represents a non-transition element like tin, aluminum, or silicon. These materials crystallize in the A15 cubic structure, which features orthogonal chains of transition metal atoms running through the lattice. This unique atomic arrangement is fundamental to their high superconducting performance, as it facilitates a high density of states at the Fermi level, contributing to elevated transition temperatures and robust upper critical fields. Among this group, niobium-tin (Nb3Sn) stands out as the preeminent industrial material, serving as the workhorse for high-field superconducting magnets. Unlike conventional niobium-titanium alloys, which reach their operational limits in high-magnetic-field environments, A15 compounds maintain their superconducting state under significantly more intense magnetic flux. This capability makes them indispensable for advanced technological applications, including the powerful magnets required for magnetic resonance imaging (MRI) systems and the massive fusion reactors like ITER. While these materials are inherently brittle, necessitating sophisticated manufacturing techniques such as the bronze-process or internal-tin-process to form multifilamentary wires, their role in enabling high-field physics remains unmatched. Ongoing research continues to explore ways to enhance their strain tolerance and current-carrying capacity, ensuring that A15 superconductors remain central to the future of high-energy particle accelerators and large-scale energy infrastructure.

Members

Top A15 Superconductors

Ranked by data richness — literature synthesis coverage, multi-source DFT corroboration, and patent activity.

FormulaBand GapBest EAH (eV/atom)StabilityDFT SourcesRecipes
Nb3SiMetallic / not reported0.0103Stable11
Nb3SnMetallic / not reported0.0000Stable10
NbSi2Metallic / not reported0.0000Stable11
NbSn2Metallic / not reported0.0000Stable10
V2Si0.10 eV0.0992Metastable—0
AlVMetallic / not reported0.0000Unstable10
NbSiMetallic / not reported0.2974Unstable10
NbSnMetallic / not reported0.1500Unstable10
AlV2Metallic / not reported0.0000Stable10
Nb5Si3Metallic / not reported0.0000Stable10
AlV3Metallic / not reported0.0000Stable10
Nb2AlMetallic / not reported0.0000Stable10
NbAlMetallic / not reported0.1075Unstable10
NbGaMetallic / not reported0.1761Unstable10
NbGeMetallic / not reported0.1830Unstable10
NbGe2Metallic / not reported0.0000Stable10
V3SiMetallic / not reported0.0000Stable10
VGaMetallic / not reported0.0605Metastable10
VGeMetallic / not reported0.0988Unstable10
VGe2Metallic / not reported0.0000Metastable10
VSiMetallic / not reported0.2027Unstable10
VSi2Metallic / not reported0.0000Stable10
VSnMetallic / not reported0.2909Unstable10
Nb3AlMetallic / not reported0.0416Metastable10
Nb3GeMetallic / not reported0.0494Metastable10
V3SnMetallic / not reported0.0000Stable10
Al3VMetallic / not reported0.0000Stable10
NbAl3Metallic / not reported0.0000Stable10
NbGa3Metallic / not reported0.0000Stable10
Nb3Si2Metallic / not reported0.0189Near hull (likely stable)—0
VSn2Metallic / not reported0.0000Stable10
Al8V5Metallic / not reported0.0181Stable10
V3GeMetallic / not reported0.0000Stable10
Nb2SnMetallic / not reported0.3530Above hull—0
Nb3Ga2Metallic / not reported0.0000Stable10
Nb5Ge3Metallic / not reported0.0000Stable10
Nb3GaMetallic / not reported0.0494Metastable10
VGe3Metallic / not reported0.3424Unstable10
Al2VMetallic / not reported0.1266Above hull—0
Nb2GaMetallic / not reported0.6474Above hull—0
Nb2GeMetallic / not reported0.0869Metastable—0
Nb2SiMetallic / not reported0.0125Near hull (likely stable)—0
NbAl2Metallic / not reported0.1103Above hull—0
NbGa2Metallic / not reported0.2333Above hull—0
NbSi3Metallic / not reported0.4682Above hull—0
V2GaMetallic / not reported0.0000On hull (stable)—0
V2GeMetallic / not reported0.0164Near hull (likely stable)—0
V2SnMetallic / not reported0.0000On hull (stable)—0
VGa3Metallic / not reported0.0404Metastable10
VSi3Metallic / not reported0.4761Above hull—0
Reference

Frequently Asked Questions

How many a15 superconductors are in the database?

682 a15 superconductors are tracked, of which 0 have multi-source DFT validation and 12 have documented synthesis routes.

More questions
What is the most data-rich a15 superconductor?
Nb3Si is the most thoroughly characterized, with 63 reported structures.
Which a15 superconductor has the widest band gap?
Among the top compounds, V2Si has the widest reported DFT band gap (0.10 eV).
Why are A15 superconductors considered brittle?
A15 compounds are intermetallic phases with complex crystal structures that lack the ductility found in metallic solid solutions, making them susceptible to fracture under mechanical strain.
How does Nb3Sn compare to NbTi in magnetic applications?
Nb3Sn can operate at significantly higher magnetic field strengths than NbTi, allowing for the creation of more powerful magnets in applications where NbTi would lose its superconductivity.
What is the significance of the A15 crystal structure?
The structure features orthogonal chains of transition metal atoms that create a high density of electronic states, which is essential for achieving high superconducting transition temperatures.
Are A15 superconductors used in commercial technology?
Yes, they are widely utilized in high-field magnets for medical MRI machines and are critical components in the development of large-scale fusion energy research facilities.
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