ZnS

zinc sulfide · zinc blende, wurtzite

Zinc sulfide is a stable, widely used semiconductor material that serves as a cornerstone in the development of optical and electronic technologies.

Crystal structure of ZnS
Ground-state structure · Materials Project
Overview

About zinc sulfide

Zinc sulfide is a foundational II-VI semiconductor known for its robust thermodynamic stability. As a highly studied material with a vast array of documented structural arrangements, it serves as a critical model system for understanding crystal growth and electronic behavior in binary chalcogenides.

Its unique semiconducting character makes it indispensable for high-performance optical and optoelectronic devices. The material is widely valued for its ability to maintain structural integrity under various conditions, supporting its role in advanced thin-film technologies and light-emitting components.

At a glance

Key Properties

Cross-validated computational properties for zinc sulfide, aggregated across 4 databases.

Band Gap

0.11–2.09 eV
Range across DFT structures

Energy Above Hull

0.000 eV/atom
Best (lowest) across sources

Stability

On hull (stable)
2 DFT sources

Structures

344
4 databases, 21 space groups
Synthesis

Synthesis Routes

Literature-extracted synthesis procedures targeting ZnS.

Sol Gel
Procedure available · ceder_sol_gel
Solid State
Procedure available · ceder_solid_state
Solid State
Procedure available · ceder_solid_state
Solid State
Procedure available · ceder_solid_state
Sol Gel
Procedure available · ceder_sol_gel
Sol Gel
Procedure available · ceder_sol_gel
Uses

Applications

Where zinc sulfide is used.

Phosphors for cathode ray tubesInfrared optical windowsPhotovoltaic cellsLight-emitting diodesPigments and coatings
Intellectual Property

Patent Landscape

12 patents reference ZnS or close compositional variants.

PatentTitleAssigneeGranted
6656260ZnS-series sintered material and method for producing the same, target using the ZnS-series sintered material,
5498369Method of manufacturing ZnS particles
9696317Greener process to synthesize water-soluble Mn2+-doped CdSSe(ZnS) core(shell) nanocrystals for ratiometric tem
6297190ZnS photocatalyst, preparation therefor and method for producing hydrogen by use of the same
9163130Method for the production of ZnS particles having a metal oxide coating and a cobalt content, products obtaine
9202867Nanocrystals containing CdTe core with CdS and ZnS coatings
10105687Heterostructured Bi2S3—ZnS photocatalysts and methods thereof
9559411Method for producing infrared ZnS domes
5686195Process for an improved laminate of ZnSe and ZnS
5476549Process for an improved laminate of ZnSe and ZnS
Reference

Frequently Asked Questions

Common questions about zinc sulfide, answered from cross-validated data.

What is ZnS?

Zinc sulfide is a stable, widely used semiconductor material that serves as a cornerstone in the development of optical and electronic technologies.

More questions
What is ZnS used for?
zinc sulfide (ZnS) is used in phosphors for cathode ray tubes, infrared optical windows, photovoltaic cells, light-emitting diodes, and pigments and coatings.
What is the band gap of ZnS?
zinc sulfide (ZnS) has a DFT-computed band gap of 0.11–2.09 eV across 344 reported structures.
Is ZnS a metal, semiconductor, or insulator?
With a band gap up to 2.09 eV it is a semiconductor.
Is ZnS thermodynamically stable?
Yes — zinc sulfide (ZnS) sits on the convex hull (energy above hull 0 eV/atom), i.e. on hull (stable).
How many polymorphs of ZnS are known?
344 structures of ZnS are reported across 4 databases, spanning 21 distinct space groups.
How is ZnS synthesized?
Literature-reported routes for ZnS include sol gel, solid state (10 procedures documented).
What elements does ZnS contain?
zinc sulfide (ZnS) contains S and Zn (2 elements).
Where does the data for ZnS come from?
ZnS data is cross-referenced from latticegraph.
Comparison

How It Compares

Within the ii-vi semiconductors class.

Within the II-VI semiconductor family, zinc sulfide stands out as a primary, highly stable benchmark compared to heavier counterparts like cadmium sulfide or cadmium telluride. While siblings such as CdS share similar structural motifs, zinc sulfide is distinguished by its widespread availability and its status as one of the most extensively characterized materials in its class.

Explore

Related Compounds

Other II-VI Semiconductors in the database.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

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