SrAl12O19

Strontium hexaaluminate · Sr-beta-alumina

Strontium hexaaluminate is a thermally robust, insulating oxide ceramic used primarily as a stable support material in high-temperature catalytic systems.

Crystal structure of SrAl12O19 (hexagonal, P63mc (No. 186))
Ground-state structure · Materials Project
Overview

About Strontium hexaaluminate

Strontium hexaaluminate is a structurally complex oxide that functions as a wide-gap insulator. Its robust thermodynamic stability makes it a highly reliable candidate for demanding industrial environments where structural integrity under thermal stress is paramount.

Because of its refractory nature, this material is primarily utilized in high-temperature catalytic processes and as a stable ceramic substrate. Its ability to maintain its phase identity at elevated temperatures allows it to serve as a long-lasting support for active catalytic species.

At a glance

Key Properties

Cross-validated computational properties for Strontium hexaaluminate, aggregated across 2 databases.

Band Gap

4.46 eV
Range across DFT structures

Energy Above Hull

0.002 eV/atom
Best (lowest) across sources

Stability

Near hull (likely stable)
1 DFT source

Structures

3
2 databases, 2 space groups
Crystallography

Reported Structures

Lowest-energy structures reported for SrAl12O19, ranked by energy above hull.

Space GroupCrystal SystemBand Gap (eV)E above hull (eV/atom)E/atom (eV)Density (g/cm³)
P63mc (No. 186)hexagonal4.460.0023-7.8343.92
P63/mmc (No. 194)hexagonal4.450.0028-7.8333.91
P63/mmc (No. 194)
Synthesis

Synthesis Routes

Literature-extracted synthesis procedures targeting SrAl12O19.

Sol-Gel
Procedure available · ceder_solid_state
Sol-Gel
Procedure available · ceder_solid_state
Sol-Gel
Procedure available · ceder_solid_state
Sol-Gel
Procedure available · ceder_solid_state
Sol-Gel
Procedure available · ceder_solid_state
Uses

Applications

Where Strontium hexaaluminate is used.

High-temperature catalytic supportsRefractory ceramicsThermal barrier coatingsPhosphor host materials
Reference

Frequently Asked Questions

Common questions about Strontium hexaaluminate, answered from cross-validated data.

What is SrAl12O19?

Strontium hexaaluminate is a thermally robust, insulating oxide ceramic used primarily as a stable support material in high-temperature catalytic systems.

More questions
What is SrAl12O19 used for?
Strontium hexaaluminate (SrAl12O19) is used in high-temperature catalytic supports, refractory ceramics, thermal barrier coatings, and phosphor host materials.
What is the band gap of SrAl12O19?
Strontium hexaaluminate (SrAl12O19) has a DFT-computed band gap of 4.46 eV across 3 reported structures.
Is SrAl12O19 a metal, semiconductor, or insulator?
With a wide band gap up to 4.46 eV it is an insulator / wide-band-gap material.
Is SrAl12O19 thermodynamically stable?
Strontium hexaaluminate (SrAl12O19) has a lowest energy above hull of 0.002 eV/atom (near hull (likely stable)).
What is the crystal structure of SrAl12O19?
The lowest-energy reported polymorph of Strontium hexaaluminate (SrAl12O19) is hexagonal symmetry, space group P63mc (No. 186).
What is the density of SrAl12O19?
The computed density of the ground-state structure of Strontium hexaaluminate (SrAl12O19) is 3.92 g/cm³.
How many polymorphs of SrAl12O19 are known?
3 structures of SrAl12O19 are reported across 2 databases, spanning 2 distinct space groups.
How is SrAl12O19 synthesized?
Literature-reported routes for SrAl12O19 include sol-gel (5 procedures documented).
What elements does SrAl12O19 contain?
Strontium hexaaluminate (SrAl12O19) contains Al, O, and Sr (3 elements).
Where does the data for SrAl12O19 come from?
SrAl12O19 data is cross-referenced from materials_project, jarvis.
Comparison

How It Compares

Within the spinel oxide catalysts class.

Unlike transition metal-based oxides such as CuO or NiO, which are often prized for their redox activity and electronic conductivity, SrAl12O19 acts as a chemically inert and thermally stable insulator, similar to the role played by MgAl2O4 or Al2O3 in high-temperature catalyst support systems.

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Related Compounds

Other Spinel Oxide Catalysts in the database.

Data sources & attribution
  • materials_project — Data from the Materials Project. Cite: Jain et al., APL Materials 1, 011002 (2013).
  • jarvis — Data from JARVIS (NIST). Cite: Choudhary et al., npj Comp. Mater. 6, 173 (2020).

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