Sn2P2O7

tin(II) pyrophosphate · stannous pyrophosphate

Sn2P2O7 is a stable, insulating tin-based pyrophosphate used in materials research for its unique electronic and structural characteristics.

Crystal structure of Sn2P2O7
Ground-state structure · Materials Project
Overview

About tin(II) pyrophosphate

Sn2P2O7 is a thermodynamically stable inorganic compound characterized by its insulating electronic nature. As a member of the oxide family, it maintains structural integrity on the convex hull, making it a robust subject for materials science investigations into wide-band-gap systems. The compound is frequently studied for its potential in specialized optical and electronic applications where high stability is required. Its structural versatility is evidenced by the numerous reported configurations found across material databases.

At a glance

Key Properties

Cross-validated computational properties for tin(II) pyrophosphate, aggregated across 3 databases.

Band Gap

2.55–3.65 eV
Range across DFT structures

Energy Above Hull

0.000 eV/atom
Best (lowest) across sources

Stability

On hull (stable)
1 DFT source

Structures

20
3 databases, 6 space groups
Synthesis

Synthesis Routes

Literature-extracted synthesis procedures targeting Sn2P2O7.

Solid State
Procedure available · ceder_solid_state
Solid State
Procedure available · ceder_solid_state
Uses

Applications

Where tin(II) pyrophosphate is used.

optical materials researchdielectric studiessolid-state chemistry
Reference

Frequently Asked Questions

Common questions about tin(II) pyrophosphate, answered from cross-validated data.

What is Sn2P2O7?

Sn2P2O7 is a stable, insulating tin-based pyrophosphate used in materials research for its unique electronic and structural characteristics.

More questions
What is Sn2P2O7 used for?
tin(II) pyrophosphate (Sn2P2O7) is used in optical materials research, dielectric studies, and solid-state chemistry.
What is the band gap of Sn2P2O7?
tin(II) pyrophosphate (Sn2P2O7) has a DFT-computed band gap of 2.55–3.65 eV across 20 reported structures.
Is Sn2P2O7 a metal, semiconductor, or insulator?
With a wide band gap up to 3.65 eV it is an insulator / wide-band-gap material.
Is Sn2P2O7 thermodynamically stable?
Yes — tin(II) pyrophosphate (Sn2P2O7) sits on the convex hull (energy above hull 0 eV/atom), i.e. on hull (stable).
How many polymorphs of Sn2P2O7 are known?
20 structures of Sn2P2O7 are reported across 3 databases, spanning 6 distinct space groups.
How is Sn2P2O7 synthesized?
Literature-reported routes for Sn2P2O7 include solid state (2 procedures documented).
What elements does Sn2P2O7 contain?
tin(II) pyrophosphate (Sn2P2O7) contains O, P, and Sn (3 elements).
Where does the data for Sn2P2O7 come from?
Sn2P2O7 data is cross-referenced from latticegraph.
Comparison

How It Compares

Within the transparent conducting oxides class.

Unlike the highly conductive BaSnO3 or the widely utilized ZnO, Sn2P2O7 functions primarily as a wide-band-gap insulator. While many members of this class are engineered for their transparent conducting properties, Sn2P2O7 serves as a stable dielectric counterpart, offering a distinct electronic profile compared to the semiconducting or conductive oxides in the group.

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Related Compounds

Other Transparent Conducting Oxides in the database.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

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