Na2FeO2

Na2FeO2 is a metastable, semiconducting layered oxide containing sodium, iron, and oxygen that is investigated for its potential in advanced electrochemical energy storage.

Crystal structure of Na2FeO2
Ground-state structure · Materials Project
Overview

About Na2FeO2

Na2FeO2 is a member of the layered sodium transition-metal oxide family, characterized by its semiconducting electronic structure. As a metastable phase, it represents a complex arrangement of sodium, iron, and oxygen atoms that offers unique structural pathways for ion mobility.

This compound is of significant interest in the field of materials science, particularly for researchers investigating alternative cathode materials for sodium-ion batteries. Its layered architecture is a subject of ongoing study to understand how transition-metal coordination influences electrochemical performance in energy storage devices.

At a glance

Key Properties

Cross-validated computational properties for Na2FeO2, aggregated across 3 databases.

Band Gap

0.04–1.26 eV
Range across DFT structures

Energy Above Hull

0.053 eV/atom
Best (lowest) across sources

Stability

Metastable
2 DFT sources

Structures

16
3 databases, 5 space groups
Uses

Applications

Where Na2FeO2 is used.

Sodium-ion battery researchElectrochemical energy storage studies
Reference

Frequently Asked Questions

Common questions about Na2FeO2, answered from cross-validated data.

What is Na2FeO2?

Na2FeO2 is a metastable, semiconducting layered oxide containing sodium, iron, and oxygen that is investigated for its potential in advanced electrochemical energy storage.

More questions
What is Na2FeO2 used for?
Na2FeO2 is used in sodium-ion battery research and electrochemical energy storage studies.
What is the band gap of Na2FeO2?
Na2FeO2 has a DFT-computed band gap of 0.04–1.26 eV across 16 reported structures.
Is Na2FeO2 a metal, semiconductor, or insulator?
With a band gap up to 1.26 eV it is a semiconductor.
Is Na2FeO2 thermodynamically stable?
Na2FeO2 has a lowest energy above hull of 0.053 eV/atom (metastable).
How many polymorphs of Na2FeO2 are known?
16 structures of Na2FeO2 are reported across 3 databases, spanning 5 distinct space groups.
What elements does Na2FeO2 contain?
Na2FeO2 contains Fe, Na, and O (3 elements).
Where does the data for Na2FeO2 come from?
Na2FeO2 data is cross-referenced from latticegraph.
Comparison

How It Compares

Within the layered sodium transition-metal oxides class.

Within the diverse group of layered sodium transition-metal oxides, Na2FeO2 occupies a distinct niche compared to more conventional members like NaFeO2 or NaCoO2. While many of its siblings are recognized for their robust stability in battery applications, Na2FeO2 is notable for its metastable nature, which provides a different structural framework for ion intercalation compared to the more common, highly stable oxides in this class.

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Related Compounds

Other Layered Sodium Transition-Metal Oxides in the database.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

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