LiFe5O8

Lithium ferrite · Lithium iron oxide

LiFe5O8 is a semiconducting, metastable lithium iron oxide utilized in electrochemical oxygen-evolution research.

Crystal structure of LiFe5O8
Ground-state structure · Materials Project
Overview

About Lithium ferrite

LiFe5O8 is a semiconducting oxide that functions within the broader category of oxygen-evolution catalysts. As a metastable phase, it represents a specialized configuration of lithium and iron oxides that offers distinct structural pathways for catalytic surface reactions.

Its importance lies in its ability to facilitate electrochemical processes while maintaining a stable crystalline framework. Researchers utilize this material to understand how iron-rich oxide environments influence the kinetics of oxygen production in energy storage and conversion systems.

At a glance

Key Properties

Cross-validated computational properties for Lithium ferrite, aggregated across 2 databases.

Band Gap

1.04–1.37 eV
Range across DFT structures

Energy Above Hull

0.063 eV/atom
Best (lowest) across sources

Stability

Metastable
1 DFT source

Structures

6
2 databases, 4 space groups
Synthesis

Synthesis Routes

Literature-extracted synthesis procedures targeting LiFe5O8.

Sol Gel
Procedure available · ceder_sol_gel
Sol Gel
Procedure available · ceder_sol_gel
Sol Gel
Procedure available · ceder_sol_gel
Sol Gel
Procedure available · ceder_sol_gel
Sol Gel
Procedure available · ceder_sol_gel
Sol Gel
Procedure available · ceder_sol_gel
Uses

Applications

Where Lithium ferrite is used.

Oxygen-evolution catalysisMagnetic materials researchElectrochemical energy conversion
Reference

Frequently Asked Questions

Common questions about Lithium ferrite, answered from cross-validated data.

What is LiFe5O8?

LiFe5O8 is a semiconducting, metastable lithium iron oxide utilized in electrochemical oxygen-evolution research.

More questions
What is LiFe5O8 used for?
Lithium ferrite (LiFe5O8) is used in oxygen-evolution catalysis, magnetic materials research, and electrochemical energy conversion.
What is the band gap of LiFe5O8?
Lithium ferrite (LiFe5O8) has a DFT-computed band gap of 1.04–1.37 eV across 6 reported structures.
Is LiFe5O8 a metal, semiconductor, or insulator?
With a band gap up to 1.37 eV it is a semiconductor.
Is LiFe5O8 thermodynamically stable?
Lithium ferrite (LiFe5O8) has a lowest energy above hull of 0.063 eV/atom (metastable).
How many polymorphs of LiFe5O8 are known?
6 structures of LiFe5O8 are reported across 2 databases, spanning 4 distinct space groups.
How is LiFe5O8 synthesized?
Literature-reported routes for LiFe5O8 include sol gel, solid state (10 procedures documented).
What elements does LiFe5O8 contain?
Lithium ferrite (LiFe5O8) contains Fe, Li, and O (3 elements).
Where does the data for LiFe5O8 come from?
LiFe5O8 data is cross-referenced from latticegraph.
Comparison

How It Compares

Within the oxide oxygen-evolution catalysts class.

Compared to common battery cathode materials like LiCoO2 or LiMn2O4, LiFe5O8 occupies a niche role within the oxide catalyst class. While materials like NiO are frequently studied for their simple binary structure, LiFe5O8 provides a more complex, iron-heavy lattice that serves as an alternative for specific catalytic environments where traditional lithium-cobalt or lithium-manganese oxides may not be optimized.

Explore

Related Compounds

Other Oxide Oxygen-Evolution Catalysts in the database.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

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