Li2Si2O5

Lithium disilicate · Lithium silicate glass-ceramic

Lithium disilicate is a stable, insulating lithium silicate ceramic prized for its exceptional mechanical strength and use in restorative dentistry.

Crystal structure of Li2Si2O5
Ground-state structure · Materials Project
Overview

About Lithium disilicate

Lithium disilicate is a thermodynamically stable lithium oxide that functions as a wide-gap insulator. Its robust structural framework and chemical stability make it a highly reliable material for demanding engineering and medical environments.

Because of its unique ability to be processed into glass-ceramics, this compound is widely utilized where high mechanical strength and aesthetic translucency are required. It serves as a cornerstone in modern materials science for applications requiring durable, non-conductive ceramic components.

At a glance

Key Properties

Cross-validated computational properties for Lithium disilicate, aggregated across 3 databases.

Band Gap

5.15–5.41 eV
Range across DFT structures

Energy Above Hull

0.000 eV/atom
Best (lowest) across sources

Stability

On hull (stable)
2 DFT sources

Structures

6
3 databases, 2 space groups
Synthesis

Synthesis Routes

Literature-extracted synthesis procedures targeting Li2Si2O5.

Sol Gel
Procedure available · ceder_sol_gel
Solid State
Procedure available · ceder_solid_state
Solid State
Procedure available · ceder_solid_state
Solid State
Procedure available · ceder_solid_state
Solid State
Procedure available · ceder_solid_state
Solid State
Procedure available · ceder_solid_state
Uses

Applications

Where Lithium disilicate is used.

Dental crownsDental bridgesGlass-ceramic fabricationHigh-strength ceramic components
Reference

Frequently Asked Questions

Common questions about Lithium disilicate, answered from cross-validated data.

What is Li2Si2O5?

Lithium disilicate is a stable, insulating lithium silicate ceramic prized for its exceptional mechanical strength and use in restorative dentistry.

More questions
What is Li2Si2O5 used for?
Lithium disilicate (Li2Si2O5) is used in dental crowns, dental bridges, glass-ceramic fabrication, and high-strength ceramic components.
What is the band gap of Li2Si2O5?
Lithium disilicate (Li2Si2O5) has a DFT-computed band gap of 5.15–5.41 eV across 6 reported structures.
Is Li2Si2O5 a metal, semiconductor, or insulator?
With a wide band gap up to 5.41 eV it is an insulator / wide-band-gap material.
Is Li2Si2O5 thermodynamically stable?
Yes — Lithium disilicate (Li2Si2O5) sits on the convex hull (energy above hull 0 eV/atom), i.e. on hull (stable).
How many polymorphs of Li2Si2O5 are known?
6 structures of Li2Si2O5 are reported across 3 databases, spanning 2 distinct space groups.
How is Li2Si2O5 synthesized?
Literature-reported routes for Li2Si2O5 include sol gel, solid state (7 procedures documented).
What elements does Li2Si2O5 contain?
Lithium disilicate (Li2Si2O5) contains Li, O, and Si (3 elements).
Where does the data for Li2Si2O5 come from?
Li2Si2O5 data is cross-referenced from latticegraph.
Comparison

How It Compares

Within the lithium oxides class.

Unlike the transition-metal-based lithium oxides such as LiCoO2 or LiMn2O4, which are primarily valued for their electrochemical activity in battery cathodes, Li2Si2O5 acts as a stable structural ceramic. While it shares the lithium-rich oxide classification with compounds like Li2O and Li4SiO4, its silicate-based network provides superior mechanical properties and chemical resistance compared to the more reactive or ionic lithium-rich oxides.

Explore

Related Compounds

Other Lithium Oxides in the database.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

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