CdCO

CdCO is a semimetallic oxide compound known for its structural diversity and metastable nature within the transparent conducting oxide class.

Overview

About CdCO

CdCO is an intriguing inorganic compound categorized within the family of transparent conducting oxides. Characterized by a near-zero-gap electronic structure, it exhibits semimetallic behavior that distinguishes it from typical wide-gap insulators found in this material class. Due to its thermodynamic position above the hull, it is considered a metastable phase, which presents unique challenges and opportunities for synthesis and characterization.

Despite its instability, the compound has been the subject of significant investigation, with numerous reported structures across major materials databases. Its electronic nature suggests potential interest for researchers exploring unconventional charge transport mechanisms in oxide systems, even if its practical deployment remains limited by its thermodynamic state compared to more robust oxide materials.

At a glance

Key Properties

Cross-validated computational properties for CdCO, aggregated across 4 databases.

Band Gap

0.02 eV
Range across DFT structures

Energy Above Hull

1.513 eV/atom
Best (lowest) across sources

Stability

Above hull
2 DFT sources

Structures

11
4 databases, 7 space groups
Crystallography

Reported Structures

Lowest-energy structures reported for CdCO, ranked by energy above hull.

Space GroupCrystal SystemBand Gap (eV)E above hull (eV/atom)E/atom (eV)Density (g/cm³)
C2/c (No. 15)monoclinic0.021.5126-6.3930.94
No. 0unknown0.68
No. 0unknown0.68
No. 0unknown0.68
Pmm2 (No. 25)Orthorhombic5.43
Cm (No. 8)Monoclinic4.79
Cm (No. 8)Monoclinic5.70
Cm (No. 8)Monoclinic5.86
Pm (No. 6)Monoclinic5.89
P21/m (No. 11)Monoclinic6.25
P-6m2 (No. 187)
Reference

Frequently Asked Questions

Common questions about CdCO, answered from cross-validated data.

What is CdCO?

CdCO is a semimetallic oxide compound known for its structural diversity and metastable nature within the transparent conducting oxide class.

More questions
What is the band gap of CdCO?
CdCO has a DFT-computed band gap of 0.02 eV across 11 reported structures.
Is CdCO a metal, semiconductor, or insulator?
With a near-zero band gap it behaves as a (semi)metal.
Is CdCO thermodynamically stable?
CdCO has a lowest energy above hull of 1.513 eV/atom (above hull).
What is the crystal structure of CdCO?
The lowest-energy reported polymorph of CdCO is monoclinic symmetry, space group C2/c (No. 15).
What is the density of CdCO?
The computed density of the ground-state structure of CdCO is 0.94 g/cm³.
How many polymorphs of CdCO are known?
11 structures of CdCO are reported across 4 databases, spanning 7 distinct space groups.
What elements does CdCO contain?
CdCO contains C, Cd, and O (3 elements).
Where does the data for CdCO come from?
CdCO data is cross-referenced from materials_project, cod, mpaloe, jarvis.
Comparison

How It Compares

Within the transparent conducting oxides class.

Unlike the highly stable and widely utilized ZnO, which serves as a benchmark for transparent conducting oxides, CdCO occupies a more precarious thermodynamic position. While siblings like BaSnO3 and ZnGa2O4 are prized for their structural robustness and predictable electronic performance, CdCO is defined by its semimetallic character, setting it apart from the insulating or semiconducting nature of most other members in this class.

Explore

Related Compounds

Other Transparent Conducting Oxides in the database.

Data sources & attribution
  • materials_project — Data from the Materials Project. Cite: Jain et al., APL Materials 1, 011002 (2013).
  • cod — Data from the Crystallography Open Database. Cite: Grazulis et al., Nucleic Acids Res. 40, D420 (2012).
  • mpaloe — Data from mpaloe.
  • jarvis — Data from JARVIS (NIST). Cite: Choudhary et al., npj Comp. Mater. 6, 173 (2020).

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