B4C

Boron carbide · Black diamond

Boron carbide is an exceptionally hard, stable ceramic compound used primarily for its durability in protective and abrasive applications.

Crystal structure of B4C
Ground-state structure · Materials Project
Overview

About Boron carbide

Boron carbide is a robust, thermodynamically stable ceramic material composed of boron and carbon. As a wide-band-gap insulator, it exhibits exceptional structural integrity and chemical resistance, making it a cornerstone of modern materials science for demanding environments.

Its unique combination of low density and extreme hardness ensures its place as a critical component in ballistic protection and heavy-duty industrial applications. Its stability on the convex hull confirms its reliability as a structural material that maintains performance under significant mechanical stress.

At a glance

Key Properties

Cross-validated computational properties for Boron carbide, aggregated across 3 databases.

Band Gap

1.51–3.04 eV
Range across DFT structures

Energy Above Hull

0.000 eV/atom
Best (lowest) across sources

Stability

On hull (stable)
2 DFT sources

Structures

68
3 databases, 16 space groups
Synthesis

Synthesis Routes

Literature-extracted synthesis procedures targeting B4C.

Solid State
Procedure available · ceder_solid_state
Uses

Applications

Where Boron carbide is used.

Ballistic armorAbrasive blasting nozzlesNuclear reactor control rodsCeramic armor platingWear-resistant industrial components
Intellectual Property

Patent Landscape

6 patents reference B4C or close compositional variants.

PatentTitleAssigneeGranted
7550029Recycling method for Al—B4C composite materials
8377369Density and hardness pressureless sintered and post-HIPed B4C
5039633B4C/Al cermets and method for making same
11906010Sacrificial materials to improve chemical vapor infiltration of B4C loaded preforms
11795111Electro-conductive B4C-TiB2 composite ceramic and preparation method thereof
11364654Indirect additive manufacturing process for producing SiC—B4C—Si composites
Reference

Frequently Asked Questions

Common questions about Boron carbide, answered from cross-validated data.

What is B4C?

Boron carbide is an exceptionally hard, stable ceramic compound used primarily for its durability in protective and abrasive applications.

More questions
What is B4C used for?
Boron carbide (B4C) is used in ballistic armor, abrasive blasting nozzles, nuclear reactor control rods, ceramic armor plating, and wear-resistant industrial components.
What is the band gap of B4C?
Boron carbide (B4C) has a DFT-computed band gap of 1.51–3.04 eV across 68 reported structures.
Is B4C a metal, semiconductor, or insulator?
With a wide band gap up to 3.04 eV it is an insulator / wide-band-gap material.
Is B4C thermodynamically stable?
Yes — Boron carbide (B4C) sits on the convex hull (energy above hull 0 eV/atom), i.e. on hull (stable).
How many polymorphs of B4C are known?
68 structures of B4C are reported across 3 databases, spanning 16 distinct space groups.
How is B4C synthesized?
Literature-reported routes for B4C include solid state.
What elements does B4C contain?
Boron carbide (B4C) contains B and C (2 elements).
Where does the data for B4C come from?
B4C data is cross-referenced from latticegraph.
Comparison

How It Compares

Within the carbide hard materials class.

Within the class of carbide hard materials, boron carbide is distinguished by its superior hardness and lightweight profile compared to metallic carbides like ZrC or HfC. While silicon-based carbides such as SiC are widely utilized for their thermal conductivity and semiconductor properties, boron carbide remains the preferred choice for applications where maximum hardness and impact resistance are the primary engineering requirements.

Explore

Related Compounds

Other Carbide Hard Materials in the database.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

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