VCl4
Vanadium tetrachloride · Vanadium(IV) chloride
Vanadium tetrachloride is a stable, semiconducting chemical compound frequently utilized as a reactive precursor in industrial synthesis and catalysis.

About Vanadium tetrachloride
Vanadium tetrachloride is a semiconducting inorganic compound that exists as a thermodynamically stable phase. Its structural integrity is well-documented, with extensive experimental data confirming its reliable formation and presence within materials science research.
This compound serves as a vital reagent in various synthetic pathways, particularly in the production of specialized polymers and other vanadium-based chemical species. Its ability to act as a precursor makes it an essential building block in industrial and laboratory-scale chemical manufacturing.
Key Properties
Cross-validated computational properties for Vanadium tetrachloride, aggregated across 3 databases.
Band GapEnergy needed to move an electron from the valence band to the conduction band. Lower or zero values tend to behave more metallic; larger gaps are more insulating or semiconducting.
Energy Above HullThermodynamic distance from the most stable set of competing phases. 0 eV/atom is on the convex hull; small positive values may still be experimentally accessible.
StabilityA plain-language summary of the best reported energy-above-hull result. It reflects whether the lowest-energy structure is on, near, or far from the stability hull.
StructuresCount of reported calculated crystal structures for this formula, including alternate polymorphs, source databases, and observed space groups.
Applications
Where Vanadium tetrachloride is used.
Frequently Asked Questions
Common questions about Vanadium tetrachloride, answered from cross-validated data.
What is VCl4?
Vanadium tetrachloride is a stable, semiconducting chemical compound frequently utilized as a reactive precursor in industrial synthesis and catalysis.
What is VCl4 used for?
What is the band gap of VCl4?
Is VCl4 a metal, semiconductor, or insulator?
Is VCl4 thermodynamically stable?
How many polymorphs of VCl4 are known?
What elements does VCl4 contain?
Where does the data for VCl4 come from?
How It Compares
As a thermodynamically stable semiconducting halide, this compound represents a key reference point for vanadium-based chemistry, offering predictable reactivity and structural consistency in synthetic applications.
Data sources & attribution
- latticegraph — Lattice Graph Materials Intelligence Platform
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