TiCl4
Titanium tetrachloride · Tetrachlorotitanium, Titanium(IV) chloride
Titanium tetrachloride is a stable, insulating metal halide used extensively as a chemical precursor and industrial catalyst.
About Titanium tetrachloride
Titanium tetrachloride is a highly significant inorganic compound characterized by its insulating electronic nature and robust thermodynamic stability. As a member of the metal halide family, it serves as a critical precursor in chemical synthesis and materials processing.
Its importance lies in its reactivity and role as a fundamental building block for advanced materials. It is widely utilized in the manufacturing of titanium-based pigments and as a primary catalyst in the polymerization of olefins, playing a central role in modern chemical manufacturing.
Key Properties
Cross-validated computational properties for Titanium tetrachloride, aggregated across 4 databases.
Band GapEnergy needed to move an electron from the valence band to the conduction band. Lower or zero values tend to behave more metallic; larger gaps are more insulating or semiconducting.
Energy Above HullThermodynamic distance from the most stable set of competing phases. 0 eV/atom is on the convex hull; small positive values may still be experimentally accessible.
StabilityA plain-language summary of the best reported energy-above-hull result. It reflects whether the lowest-energy structure is on, near, or far from the stability hull.
StructuresCount of reported calculated crystal structures for this formula, including alternate polymorphs, source databases, and observed space groups.
Applications
Where Titanium tetrachloride is used.
Patent Landscape
9 patents reference TiCl4 or close compositional variants.
| Patent | Title | Assignee | Granted |
|---|---|---|---|
| 4125586 | Removal of AlCl.sub.3 from crude TiCl.sub.4 by addition of H.sub.2 O and NaCl | — | — |
| 8906340 | Purification of TiCl4 through the production of new co-products | — | — |
| 5926737 | Use of TiCl.sub.4 etchback process during integrated CVD-Ti/TiN wafer processing | — | — |
| 5348587 | Apparatus for elimination of low temperature ammonia salts in TiCl.sub.4 NH.sub.3 CVD reaction | — | — |
| 8889094 | Purification of TiCl4 through the production of new co-products | — | — |
| 4021533 | Manufacture of titanium dioxide by the sulphate process using nuclei formed by steam hydrolysis of TiCl.sub.4 | — | — |
| 7914600 | Continuous production of titanium by the metallothermic reduction of TiCl4 | — | — |
| 5271963 | Elimination of low temperature ammonia salt in TiCl.sub.4 NH.sub.3 CVD reaction | — | — |
| 4731230 | Process for the preparation of TiCl.sub.4 | — | — |
Frequently Asked Questions
Common questions about Titanium tetrachloride, answered from cross-validated data.
What is TiCl4?
Titanium tetrachloride is a stable, insulating metal halide used extensively as a chemical precursor and industrial catalyst.
What is TiCl4 used for?
What is the band gap of TiCl4?
Is TiCl4 a metal, semiconductor, or insulator?
Is TiCl4 thermodynamically stable?
How many polymorphs of TiCl4 are known?
What elements does TiCl4 contain?
Where does the data for TiCl4 come from?
How It Compares
As a thermodynamically stable and well-documented compound, titanium tetrachloride serves as a primary reference point for titanium halides, representing a standard for reactivity and industrial utility in its class.
Data sources & attribution
- latticegraph — Lattice Graph Materials Intelligence Platform
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