SiS2

Silicon disulfide · Silicon(IV) sulfide

Silicon disulfide is a stable, insulating inorganic compound composed of silicon and sulfur that is widely studied for its structural properties.

SSi
Crystal structure of SiS2
Ground-state structure · Materials Project
Overview

About Silicon disulfide

Silicon disulfide is a thermodynamically stable compound that exists as a wide-gap insulator. Its unique structural chemistry is highlighted by its presence on the convex hull, indicating significant stability under standard conditions.

This material is a subject of extensive structural investigation, with numerous reported configurations across scientific databases. Its insulating electronic character and distinct bonding architecture make it a valuable subject for research into silicon-sulfur chemistry and specialized materials development.

At a glance

Key Properties

Cross-validated computational properties for Silicon disulfide, aggregated across 3 databases.

Band Gap

2.88–3.39 eV
Range across DFT structures

Energy Above Hull

0.000 eV/atom
Best (lowest) across sources

Stability

On hull (stable)
2 DFT sources

Structures

88
3 databases, 17 space groups
Synthesis

Synthesis Routes

Literature-extracted synthesis procedures targeting SiS2.

Sol Gel
Procedure available · ceder_sol_gel
Sol Gel
Procedure available · ceder_sol_gel
Solid State
Procedure available · ceder_solid_state
Uses

Applications

Where Silicon disulfide is used.

Chemical synthesis reagentSolid-state electrolyte researchPrecursor for silicon-based materials
Reference

Frequently Asked Questions

Common questions about Silicon disulfide, answered from cross-validated data.

What is SiS2?

Silicon disulfide is a stable, insulating inorganic compound composed of silicon and sulfur that is widely studied for its structural properties.

More questions
What is SiS2 used for?
Silicon disulfide (SiS2) is used in chemical synthesis reagent, solid-state electrolyte research, and precursor for silicon-based materials.
What is the band gap of SiS2?
Silicon disulfide (SiS2) has a DFT-computed band gap of 2.88–3.39 eV across 88 reported structures.
Is SiS2 a metal, semiconductor, or insulator?
With a wide band gap up to 3.39 eV it is an insulator / wide-band-gap material.
Is SiS2 thermodynamically stable?
Yes — Silicon disulfide (SiS2) sits on the convex hull (energy above hull 0 eV/atom), i.e. on hull (stable).
How many polymorphs of SiS2 are known?
88 structures of SiS2 are reported across 3 databases, spanning 17 distinct space groups.
How is SiS2 synthesized?
Literature-reported routes for SiS2 include sol gel, solid state (3 procedures documented).
What elements does SiS2 contain?
Silicon disulfide (SiS2) contains S and Si (2 elements).
Where does the data for SiS2 come from?
SiS2 data is cross-referenced from latticegraph.
Comparison

How It Compares

As a distinct silicon-based chalcogenide, silicon disulfide serves as a foundational reference point for sulfur-containing inorganic compounds. Its stability and insulating nature distinguish it from more conductive or reactive chalcogenide systems, positioning it as a key material for understanding the bonding behavior of group 14 elements with sulfur.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

Analyze SiS2 in the Lattice Graph platform

Polymorph comparison, confidence scoring, supply-chain risk, and patent monitoring — across 53 integrated data sources.

Explore the Platform →