SeO2

Selenium dioxide · Selenous anhydride

Selenium dioxide is a stable, insulating oxide widely utilized as a specialized oxidizing agent in chemical synthesis.

OSe
Crystal structure of SeO2
Ground-state structure · Materials Project
Overview

About Selenium dioxide

Selenium dioxide is a thermodynamically stable oxide that functions as a wide-band-gap insulator. It is characterized by a high degree of structural diversity, with numerous reported configurations that highlight its versatile coordination chemistry in the solid state.

As a primary reagent in organic chemistry, this compound is valued for its specific reactivity in oxidation processes. Its stability and electronic profile make it a foundational material for researchers investigating selenium-based chemical transformations.

At a glance

Key Properties

Cross-validated computational properties for Selenium dioxide, aggregated across 4 databases.

Band Gap

3.24–3.44 eV
Range across DFT structures

Energy Above Hull

0.000 eV/atom
Best (lowest) across sources

Stability

On hull (stable)
2 DFT sources

Structures

147
4 databases, 24 space groups
Uses

Applications

Where Selenium dioxide is used.

Organic synthesisOxidizing agentCatalysisGlass manufacturing
Reference

Frequently Asked Questions

Common questions about Selenium dioxide, answered from cross-validated data.

What is SeO2?

Selenium dioxide is a stable, insulating oxide widely utilized as a specialized oxidizing agent in chemical synthesis.

More questions
What is SeO2 used for?
Selenium dioxide (SeO2) is used in organic synthesis, oxidizing agent, catalysis, and glass manufacturing.
What is the band gap of SeO2?
Selenium dioxide (SeO2) has a DFT-computed band gap of 3.24–3.44 eV across 147 reported structures.
Is SeO2 a metal, semiconductor, or insulator?
With a wide band gap up to 3.44 eV it is an insulator / wide-band-gap material.
Is SeO2 thermodynamically stable?
Yes — Selenium dioxide (SeO2) sits on the convex hull (energy above hull 0 eV/atom), i.e. on hull (stable).
How many polymorphs of SeO2 are known?
147 structures of SeO2 are reported across 4 databases, spanning 24 distinct space groups.
What elements does SeO2 contain?
Selenium dioxide (SeO2) contains O and Se (2 elements).
Where does the data for SeO2 come from?
SeO2 data is cross-referenced from latticegraph.
Comparison

How It Compares

As a standalone oxide of selenium, this compound serves as the definitive reference point for its chemical class, demonstrating the unique structural and electronic behaviors typical of chalcogen oxides.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

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