SF6

Sulfur hexafluoride · SF6

Sulfur hexafluoride is a chemically inert, wide-gap insulating gas primarily used as a dielectric medium in high-voltage electrical infrastructure.

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Crystal structure of SF6
Ground-state structure · Materials Project
Overview

About Sulfur hexafluoride

Sulfur hexafluoride is a highly stable inorganic compound characterized by its inert nature and wide-gap insulating electronic profile. Its unique molecular structure contributes to its exceptional chemical stability, making it a critical material in industrial settings where electrical insulation is paramount.

Due to its remarkable dielectric strength and ability to quench electrical arcs, this compound serves as a vital medium in high-voltage power transmission systems. It is extensively deployed in gas-insulated switchgear and circuit breakers to ensure the safe and reliable operation of power grids.

At a glance

Key Properties

Cross-validated computational properties for Sulfur hexafluoride, aggregated across 3 databases.

Band Gap

5.81–5.96 eV
Range across DFT structures

Energy Above Hull

0.000 eV/atom
Best (lowest) across sources

Stability

On hull (stable)
2 DFT sources

Structures

19
3 databases, 7 space groups
Uses

Applications

Where Sulfur hexafluoride is used.

High-voltage circuit breakersGas-insulated switchgearElectrical transformersParticle acceleratorsMagnesium production cover gas
Intellectual Property

Patent Landscape

8 patents reference SF6 or close compositional variants.

PatentTitleAssigneeGranted
6886573Plasma cleaning gas with lower global warming potential than SF6
4331504Etching process with vibrationally excited SF.sub.6
6723153Isolation of SF6 from insulating gases in gas-insulated lines
6105631Preparation of homogeneous gas mixtures with SF.sub.6
6004377System for collecting and refining SF.sub.6 gas and method therefor
4390511Process for producing SF.sub.6 through SF.sub.5 Cl
12122685Method for preparing MoF6 based on plasma activation of SF6
6103630Adding SF.sub.6 gas to improve metal undercut for hardmask metal etching
Reference

Frequently Asked Questions

Common questions about Sulfur hexafluoride, answered from cross-validated data.

What is SF6?

Sulfur hexafluoride is a chemically inert, wide-gap insulating gas primarily used as a dielectric medium in high-voltage electrical infrastructure.

More questions
What is SF6 used for?
Sulfur hexafluoride (SF6) is used in high-voltage circuit breakers, gas-insulated switchgear, electrical transformers, particle accelerators, and magnesium production cover gas.
What is the band gap of SF6?
Sulfur hexafluoride (SF6) has a DFT-computed band gap of 5.81–5.96 eV across 19 reported structures.
Is SF6 a metal, semiconductor, or insulator?
With a wide band gap up to 5.96 eV it is an insulator / wide-band-gap material.
Is SF6 thermodynamically stable?
Yes — Sulfur hexafluoride (SF6) sits on the convex hull (energy above hull 0 eV/atom), i.e. on hull (stable).
How many polymorphs of SF6 are known?
19 structures of SF6 are reported across 3 databases, spanning 7 distinct space groups.
What elements does SF6 contain?
Sulfur hexafluoride (SF6) contains F and S (2 elements).
Where does the data for SF6 come from?
SF6 data is cross-referenced from latticegraph.
Comparison

How It Compares

As a highly stable and inert gas, sulfur hexafluoride stands out as a specialized insulating medium that is uniquely suited for high-voltage electrical applications compared to more reactive or conductive inorganic substances.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

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