RhBr3

Rhodium(III) bromide · Rhodium tribromide

Rhodium(III) bromide is a stable, semiconducting rhodium halide used as a key precursor in chemical catalysis.

Crystal structure of RhBr3
Ground-state structure · Materials Project
Overview

About Rhodium(III) bromide

Rhodium(III) bromide is a thermodynamically stable inorganic compound that exists as a semiconducting material. Its structural characteristics and relative stability make it a significant subject of study within the broader family of platinum-group metal halides and alloys.

This compound is primarily utilized in specialized chemical synthesis and as a precursor for various catalytic applications. Its ability to facilitate specific reactions is highly valued in industrial processes where rhodium-based catalysts are required for their efficiency and selectivity.

At a glance

Key Properties

Cross-validated computational properties for Rhodium(III) bromide, aggregated across 3 databases.

Band Gap

1.26 eV
Range across DFT structures

Energy Above Hull

0.000 eV/atom
Best (lowest) across sources

Stability

On hull (stable)
2 DFT sources

Structures

9
3 databases, 3 space groups
Uses

Applications

Where Rhodium(III) bromide is used.

Chemical synthesisCatalytic precursorLaboratory reagent
Reference

Frequently Asked Questions

Common questions about Rhodium(III) bromide, answered from cross-validated data.

What is RhBr3?

Rhodium(III) bromide is a stable, semiconducting rhodium halide used as a key precursor in chemical catalysis.

More questions
What is RhBr3 used for?
Rhodium(III) bromide (RhBr3) is used in chemical synthesis, catalytic precursor, and laboratory reagent.
What is the band gap of RhBr3?
Rhodium(III) bromide (RhBr3) has a DFT-computed band gap of 1.26 eV across 9 reported structures.
Is RhBr3 a metal, semiconductor, or insulator?
With a band gap up to 1.26 eV it is a semiconductor.
Is RhBr3 thermodynamically stable?
Yes — Rhodium(III) bromide (RhBr3) sits on the convex hull (energy above hull 0 eV/atom), i.e. on hull (stable).
How many polymorphs of RhBr3 are known?
9 structures of RhBr3 are reported across 3 databases, spanning 3 distinct space groups.
What elements does RhBr3 contain?
Rhodium(III) bromide (RhBr3) contains Br and Rh (2 elements).
Where does the data for RhBr3 come from?
RhBr3 data is cross-referenced from latticegraph.
Comparison

How It Compares

Within the platinum-group alloy catalysts class.

Unlike the metallic platinum-group alloys such as LaRh or BaPd, RhBr3 is a halide that exhibits semiconducting electronic behavior rather than metallic conductivity. While compounds like As2Pt or IrSe2 are often investigated for their unique structural motifs in solid-state chemistry, RhBr3 is distinguished by its role as a stable, discrete molecular-to-solid-state precursor in coordination chemistry.

Explore

Related Compounds

Other Platinum-Group Alloy Catalysts in the database.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

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