RbF2

RbF2 is a metastable, semiconducting fluoride compound that serves as a subject of fundamental research into non-standard chemical structures.

FRb
Crystal structure of RbF2
Ground-state structure · Materials Project
Overview

About RbF2

Rubidium difluoride is a metastable inorganic compound that exhibits semiconducting electronic behavior. Its existence as a fluoride phase highlights the complex coordination chemistry possible within the rubidium-fluorine system, where stoichiometry deviates from the more common stable configurations.

Because it is a metastable material, it is of significant interest to researchers studying phase transitions and high-pressure synthesis techniques. Its structural diversity, evidenced by numerous reported configurations, makes it a subject of fundamental study in solid-state chemistry.

At a glance

Key Properties

Cross-validated computational properties for RbF2, aggregated across 3 databases.

Band Gap

1.43 eV
Range across DFT structures

Energy Above Hull

0.052 eV/atom
Best (lowest) across sources

Stability

Metastable
2 DFT sources

Structures

57
3 databases, 13 space groups
Reference

Frequently Asked Questions

Common questions about RbF2, answered from cross-validated data.

What is RbF2?

RbF2 is a metastable, semiconducting fluoride compound that serves as a subject of fundamental research into non-standard chemical structures.

More questions
What is the band gap of RbF2?
RbF2 has a DFT-computed band gap of 1.43 eV across 57 reported structures.
Is RbF2 a metal, semiconductor, or insulator?
With a band gap up to 1.43 eV it is a semiconductor.
Is RbF2 thermodynamically stable?
RbF2 has a lowest energy above hull of 0.052 eV/atom (metastable).
How many polymorphs of RbF2 are known?
57 structures of RbF2 are reported across 3 databases, spanning 13 distinct space groups.
What elements does RbF2 contain?
RbF2 contains F and Rb (2 elements).
Where does the data for RbF2 come from?
RbF2 data is cross-referenced from latticegraph.
Comparison

How It Compares

As an unclassified and metastable phase, RbF2 represents a specialized case within fluoride materials, where typical stability rules are challenged. Unlike conventional ionic fluorides that favor highly stable, fixed oxidation states, this compound occupies a unique niche that demands precise synthesis conditions to maintain its structural integrity.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

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