Na2SnO3

Sodium stannate · Sodium tin oxide

Sodium stannate is a stable, semiconducting perovskite oxide used primarily as a chemical precursor and in industrial surface treatment processes.

Crystal structure of Na2SnO3
Ground-state structure · Materials Project
Overview

About Sodium stannate

Sodium stannate is a thermodynamically stable perovskite oxide that occupies a key position on the convex hull. Its semiconducting electronic character makes it an intriguing subject for materials research, particularly in the study of complex oxide systems where structural integrity is paramount. With numerous reported structures across major databases, this compound serves as a well-documented example of tin-based perovskite chemistry. Its stability and predictable behavior under various conditions allow it to function as a reliable precursor and functional material in inorganic synthesis.

At a glance

Key Properties

Cross-validated computational properties for Sodium stannate, aggregated across 3 databases.

Band Gap

2.26–2.70 eV
Range across DFT structures

Energy Above Hull

0.000 eV/atom
Best (lowest) across sources

Stability

On hull (stable)
2 DFT sources

Structures

19
3 databases, 4 space groups
Synthesis

Synthesis Routes

Literature-extracted synthesis procedures targeting Na2SnO3.

Solid State
Procedure available · ceder_solid_state
Solid State
Procedure available · ceder_solid_state
Solid State
Procedure available · ceder_solid_state
Uses

Applications

Where Sodium stannate is used.

ElectroplatingCorrosion inhibitionCeramic pigment productionChemical synthesis precursor
Reference

Frequently Asked Questions

Common questions about Sodium stannate, answered from cross-validated data.

What is Na2SnO3?

Sodium stannate is a stable, semiconducting perovskite oxide used primarily as a chemical precursor and in industrial surface treatment processes.

More questions
What is Na2SnO3 used for?
Sodium stannate (Na2SnO3) is used in electroplating, corrosion inhibition, ceramic pigment production, and chemical synthesis precursor.
What is the band gap of Na2SnO3?
Sodium stannate (Na2SnO3) has a DFT-computed band gap of 2.26–2.70 eV across 19 reported structures.
Is Na2SnO3 a metal, semiconductor, or insulator?
With a band gap up to 2.70 eV it is a semiconductor.
Is Na2SnO3 thermodynamically stable?
Yes — Sodium stannate (Na2SnO3) sits on the convex hull (energy above hull 0 eV/atom), i.e. on hull (stable).
How many polymorphs of Na2SnO3 are known?
19 structures of Na2SnO3 are reported across 3 databases, spanning 4 distinct space groups.
How is Na2SnO3 synthesized?
Literature-reported routes for Na2SnO3 include solid state (3 procedures documented).
What elements does Na2SnO3 contain?
Sodium stannate (Na2SnO3) contains Na, O, and Sn (3 elements).
Where does the data for Na2SnO3 come from?
Na2SnO3 data is cross-referenced from latticegraph.
Comparison

How It Compares

Within the perovskite oxides class.

While many perovskite oxides like LaNiO3 or BaTiO3 are widely recognized for their complex magnetic or ferroelectric behaviors, Na2SnO3 is distinguished by its role as a stable, semiconducting stannate. Unlike the transition-metal-heavy perovskites such as LaMnO3 or BiFeO3, which often exhibit strong electronic correlations, this compound provides a more chemically robust framework that is frequently utilized in industrial applications requiring consistent material properties.

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Related Compounds

Other Perovskite Oxides in the database.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

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