Na2O

Sodium oxide · Disodium oxide

Sodium oxide is a stable, semiconducting inorganic compound widely used as a reactive intermediate in chemical manufacturing.

NaO
Crystal structure of Na2O
Ground-state structure · Materials Project
Overview

About Sodium oxide

Sodium oxide is a thermodynamically stable binary compound that serves as a fundamental building block in inorganic chemistry. As a semiconducting material, it exhibits distinct electronic properties that differentiate it from more conventional ionic insulators, making it a subject of significant interest in materials science research. Its structural diversity is evidenced by numerous reported configurations across major databases.

This compound is primarily utilized as a reactive intermediate in the production of various sodium-based chemicals and glasses. Its ability to participate in complex chemical syntheses ensures its importance in industrial manufacturing and laboratory-scale chemical processing, where it acts as a potent source of sodium ions.

At a glance

Key Properties

Cross-validated computational properties for Sodium oxide, aggregated across 3 databases.

Band Gap

0.12–1.87 eV
Range across DFT structures

Energy Above Hull

0.000 eV/atom
Best (lowest) across sources

Stability

On hull (stable)
2 DFT sources

Structures

74
3 databases, 17 space groups
Synthesis

Synthesis Routes

Literature-extracted synthesis procedures targeting Na2O.

Solid State
Procedure available · ceder_solid_state
Uses

Applications

Where Sodium oxide is used.

Glass manufacturingChemical synthesisCeramic productionFluxing agent
Reference

Frequently Asked Questions

Common questions about Sodium oxide, answered from cross-validated data.

What is Na2O?

Sodium oxide is a stable, semiconducting inorganic compound widely used as a reactive intermediate in chemical manufacturing.

More questions
What is Na2O used for?
Sodium oxide (Na2O) is used in glass manufacturing, chemical synthesis, ceramic production, and fluxing agent.
What is the band gap of Na2O?
Sodium oxide (Na2O) has a DFT-computed band gap of 0.12–1.87 eV across 74 reported structures.
Is Na2O a metal, semiconductor, or insulator?
With a band gap up to 1.87 eV it is a semiconductor.
Is Na2O thermodynamically stable?
Yes — Sodium oxide (Na2O) sits on the convex hull (energy above hull 0 eV/atom), i.e. on hull (stable).
How many polymorphs of Na2O are known?
74 structures of Na2O are reported across 3 databases, spanning 17 distinct space groups.
How is Na2O synthesized?
Literature-reported routes for Na2O include solid state.
What elements does Na2O contain?
Sodium oxide (Na2O) contains Na and O (2 elements).
Where does the data for Na2O come from?
Na2O data is cross-referenced from latticegraph.
Comparison

How It Compares

As a standalone binary oxide, sodium oxide represents a critical reference point for understanding the behavior of alkali metal oxides. It occupies a unique position in the field of simple oxides, serving as a foundational material for studying the transition between ionic and semiconducting behavior in alkali-rich systems.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

Analyze Na2O in the Lattice Graph platform

Polymorph comparison, confidence scoring, supply-chain risk, and patent monitoring — across 53 integrated data sources.

Explore the Platform →