MgCl2

Magnesium chloride · Magnesium dichloride

Magnesium chloride is a stable, insulating salt widely used as a precursor for magnesium metal production and in diverse industrial chemical applications.

ClMg
Crystal structure of MgCl2
Ground-state structure · Materials Project
Overview

About Magnesium chloride

Magnesium chloride is a robust, thermodynamically stable inorganic salt characterized by its wide-band-gap insulating electronic profile. Its structural versatility is evidenced by the extensive variety of crystalline arrangements reported in scientific literature, reflecting its fundamental role in solid-state chemistry.

This compound serves as a critical precursor in the production of magnesium metal and acts as a vital component in various industrial processes. Its chemical stability and predictable reactivity make it an essential material for applications ranging from chemical manufacturing to environmental management.

At a glance

Key Properties

Cross-validated computational properties for Magnesium chloride, aggregated across 3 databases.

Band Gap

3.59–5.62 eV
Range across DFT structures

Energy Above Hull

0.000 eV/atom
Best (lowest) across sources

Stability

On hull (stable)
2 DFT sources

Structures

161
3 databases, 25 space groups
Synthesis

Synthesis Routes

Literature-extracted synthesis procedures targeting MgCl2.

Sol Gel
Procedure available · ceder_sol_gel
Uses

Applications

Where Magnesium chloride is used.

Magnesium metal productionIndustrial catalysisDe-icing and dust controlChemical synthesisTextile manufacturing
Intellectual Property

Patent Landscape

13 patents reference MgCl2 or close compositional variants.

PatentTitleAssigneeGranted
3953573Removal of boron from MgCl.sub.2 brines
4195070Preparation of a MgCl.sub.2 solution for Nalco's MgCl.sub.2 process from MgSO.sub.4 and other MgSO.sub.4 salts
4341752Method for purification and concentration of MgCl.sub.2 -brines
3953572Removal of boron from MgCl.sub.2 brines
4248838Preparation of useful MgCl.sub.2. solution with subsequent recovery of KCl from carnallite
4099965Method of using MgCl.sub.2 -KCl flux for purification of an aluminum alloy preparation
3952085Removal of boron from MgCl.sub.2 brines
6042794Process for producing anhydrous MgCl.sub.2
4743347Production of pure MgCl.sub.2 solution suitable for the production of magnesium metal from an impure magnesite
4364909Removal of Ca.sup.++ from MgCl.sub.2
Reference

Frequently Asked Questions

Common questions about Magnesium chloride, answered from cross-validated data.

What is MgCl2?

Magnesium chloride is a stable, insulating salt widely used as a precursor for magnesium metal production and in diverse industrial chemical applications.

More questions
What is MgCl2 used for?
Magnesium chloride (MgCl2) is used in magnesium metal production, industrial catalysis, de-icing and dust control, chemical synthesis, and textile manufacturing.
What is the band gap of MgCl2?
Magnesium chloride (MgCl2) has a DFT-computed band gap of 3.59–5.62 eV across 161 reported structures.
Is MgCl2 a metal, semiconductor, or insulator?
With a wide band gap up to 5.62 eV it is an insulator / wide-band-gap material.
Is MgCl2 thermodynamically stable?
Yes — Magnesium chloride (MgCl2) sits on the convex hull (energy above hull 0 eV/atom), i.e. on hull (stable).
How many polymorphs of MgCl2 are known?
161 structures of MgCl2 are reported across 3 databases, spanning 25 distinct space groups.
How is MgCl2 synthesized?
Literature-reported routes for MgCl2 include sol gel.
What elements does MgCl2 contain?
Magnesium chloride (MgCl2) contains Cl and Mg (2 elements).
Where does the data for MgCl2 come from?
MgCl2 data is cross-referenced from latticegraph.
Comparison

How It Compares

As a highly stable and well-documented inorganic salt, magnesium chloride serves as a benchmark for ionic halides, representing a fundamental structural archetype within its chemical class.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

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