LiVO2

LiVO2 is a stable, semiconducting lithium oxide compound that serves as a valuable subject for research into next-generation electrochemical materials.

Crystal structure of LiVO2
Ground-state structure · Materials Project
Overview

About LiVO2

LiVO2 is a thermodynamically stable member of the lithium oxide family that exhibits semiconducting electronic behavior. Its position on the convex hull suggests a robust structural integrity, making it a subject of significant interest for researchers investigating new electrode materials.

As a material with extensive structural data available, LiVO2 represents a versatile platform for studying ion transport and electronic properties. Its unique composition allows it to function within complex electrochemical systems, contributing to the broader understanding of lithium-based oxides in modern materials science.

At a glance

Key Properties

Cross-validated computational properties for LiVO2, aggregated across 3 databases.

Band Gap

0.02–1.57 eV
Range across DFT structures

Energy Above Hull

0.000 eV/atom
Best (lowest) across sources

Stability

On hull (stable)
2 DFT sources

Structures

44
3 databases, 12 space groups
Synthesis

Synthesis Routes

Literature-extracted synthesis procedures targeting LiVO2.

Sol Gel
Procedure available · ceder_sol_gel
Solid State
Procedure available · ceder_solid_state
Solid State
Procedure available · ceder_solid_state
Solid State
Procedure available · ceder_solid_state
Solid State
Procedure available · ceder_solid_state
Solid State
Procedure available · ceder_solid_state
Uses

Applications

Where LiVO2 is used.

Energy storage researchBattery electrode developmentSolid-state ionics
Reference

Frequently Asked Questions

Common questions about LiVO2, answered from cross-validated data.

What is LiVO2?

LiVO2 is a stable, semiconducting lithium oxide compound that serves as a valuable subject for research into next-generation electrochemical materials.

More questions
What is LiVO2 used for?
LiVO2 is used in energy storage research, battery electrode development, and solid-state ionics.
What is the band gap of LiVO2?
LiVO2 has a DFT-computed band gap of 0.02–1.57 eV across 44 reported structures.
Is LiVO2 a metal, semiconductor, or insulator?
With a band gap up to 1.57 eV it is a semiconductor.
Is LiVO2 thermodynamically stable?
Yes — LiVO2 sits on the convex hull (energy above hull 0 eV/atom), i.e. on hull (stable).
How many polymorphs of LiVO2 are known?
44 structures of LiVO2 are reported across 3 databases, spanning 12 distinct space groups.
How is LiVO2 synthesized?
Literature-reported routes for LiVO2 include sol gel, solid state (6 procedures documented).
What elements does LiVO2 contain?
LiVO2 contains Li, O, and V (3 elements).
Where does the data for LiVO2 come from?
LiVO2 data is cross-referenced from latticegraph.
Comparison

How It Compares

Within the lithium oxides class.

Within the diverse class of lithium oxides, LiVO2 occupies a distinct niche compared to widely commercialized cathodes like LiCoO2 or LiMn2O4. While those materials are primarily recognized for their high-capacity performance in batteries, LiVO2 offers a different electronic profile that complements the structural diversity seen in other members such as Li2TiO3 or Li2MnO3.

Explore

Related Compounds

Other Lithium Oxides in the database.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

Analyze LiVO2 in the Lattice Graph platform

Polymorph comparison, confidence scoring, supply-chain risk, and patent monitoring — across 53 integrated data sources.

Explore the Platform →