Li4GeO4

Li4GeO4 is a stable, insulating lithium germanium oxide used in materials research for solid-state ionics.

Crystal structure of Li4GeO4
Ground-state structure · Materials Project
Overview

About Li4GeO4

Li4GeO4 is a member of the lithium oxide family, characterized by its wide-band-gap insulating electronic nature. As a thermodynamically stable phase residing on the convex hull, it represents a robust crystalline arrangement within this chemical class.

Its structural integrity makes it a subject of interest for materials scientists investigating ion-conducting pathways. Due to its stability and electronic properties, it serves as a foundational material for exploring lithium-rich oxide systems in solid-state energy storage applications.

At a glance

Key Properties

Cross-validated computational properties for Li4GeO4, aggregated across 3 databases.

Band Gap

4.10 eV
Range across DFT structures

Energy Above Hull

0.000 eV/atom
Best (lowest) across sources

Stability

On hull (stable)
2 DFT sources

Structures

5
3 databases, 1 space group
Synthesis

Synthesis Routes

Literature-extracted synthesis procedures targeting Li4GeO4.

Solid State
Procedure available · ceder_solid_state
Solid State
Procedure available · ceder_solid_state
Uses

Applications

Where Li4GeO4 is used.

Solid-state electrolyte researchLithium-ion conductor development
Reference

Frequently Asked Questions

Common questions about Li4GeO4, answered from cross-validated data.

What is Li4GeO4?

Li4GeO4 is a stable, insulating lithium germanium oxide used in materials research for solid-state ionics.

More questions
What is Li4GeO4 used for?
Li4GeO4 is used in solid-state electrolyte research and lithium-ion conductor development.
What is the band gap of Li4GeO4?
Li4GeO4 has a DFT-computed band gap of 4.10 eV across 5 reported structures.
Is Li4GeO4 a metal, semiconductor, or insulator?
With a wide band gap up to 4.10 eV it is an insulator / wide-band-gap material.
Is Li4GeO4 thermodynamically stable?
Yes — Li4GeO4 sits on the convex hull (energy above hull 0 eV/atom), i.e. on hull (stable).
How many polymorphs of Li4GeO4 are known?
5 structures of Li4GeO4 are reported across 3 databases, spanning 1 distinct space group.
How is Li4GeO4 synthesized?
Literature-reported routes for Li4GeO4 include solid state (2 procedures documented).
What elements does Li4GeO4 contain?
Li4GeO4 contains Ge, Li, and O (3 elements).
Where does the data for Li4GeO4 come from?
Li4GeO4 data is cross-referenced from latticegraph.
Comparison

How It Compares

Within the lithium oxides class.

Unlike the transition-metal-based lithium oxides such as LiNiO2, LiMn2O4, or LiCoO2, which are primarily utilized for their redox-active cathode properties, Li4GeO4 functions more as a structural framework material. It shares closer chemical and structural motifs with Li4SiO4, both serving as important oxides where the germanium or silicon centers provide a stable anionic sublattice for lithium ion mobility.

Explore

Related Compounds

Other Lithium Oxides in the database.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

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