Li2AlCoO4

Li2AlCoO4 is a semiconducting, metastable layered lithium transition-metal oxide used in advanced materials research for potential battery applications.

Crystal structure of Li2AlCoO4
Ground-state structure · Materials Project
Overview

About Li2AlCoO4

Li2AlCoO4 is a complex oxide belonging to the class of layered lithium transition-metal materials. As a semiconducting compound, it exhibits unique electronic behavior that makes it a subject of interest for researchers investigating the next generation of energy storage materials. Its status as a metastable phase suggests a delicate structural balance that is highly sensitive to synthesis conditions. The material is characterized by a significant degree of structural diversity, as evidenced by the numerous reported configurations across various databases. This complexity highlights its potential utility in exploring ion transport pathways and electrochemical performance within solid-state systems.

At a glance

Key Properties

Cross-validated computational properties for Li2AlCoO4, aggregated across 3 databases.

Band Gap

0.03–1.79 eV
Range across DFT structures

Energy Above Hull

0.034 eV/atom
Best (lowest) across sources

Stability

Metastable
2 DFT sources

Structures

50
3 databases, 10 space groups
Uses

Applications

Where Li2AlCoO4 is used.

Battery materials researchSolid-state ionicsElectrochemical energy storage development
Reference

Frequently Asked Questions

Common questions about Li2AlCoO4, answered from cross-validated data.

What is Li2AlCoO4?

Li2AlCoO4 is a semiconducting, metastable layered lithium transition-metal oxide used in advanced materials research for potential battery applications.

More questions
What is Li2AlCoO4 used for?
Li2AlCoO4 is used in battery materials research, solid-state ionics, and electrochemical energy storage development.
What is the band gap of Li2AlCoO4?
Li2AlCoO4 has a DFT-computed band gap of 0.03–1.79 eV across 50 reported structures.
Is Li2AlCoO4 a metal, semiconductor, or insulator?
With a band gap up to 1.79 eV it is a semiconductor.
Is Li2AlCoO4 thermodynamically stable?
Li2AlCoO4 has a lowest energy above hull of 0.034 eV/atom (metastable).
How many polymorphs of Li2AlCoO4 are known?
50 structures of Li2AlCoO4 are reported across 3 databases, spanning 10 distinct space groups.
What elements does Li2AlCoO4 contain?
Li2AlCoO4 contains Al, Co, Li, and O (4 elements).
Where does the data for Li2AlCoO4 come from?
Li2AlCoO4 data is cross-referenced from latticegraph.
Comparison

How It Compares

Within the layered lithium transition-metal oxides class.

Within the broader family of layered lithium transition-metal oxides, Li2AlCoO4 occupies a distinct position compared to more established materials like LiCoO2. While LiCoO2 is a foundational cathode material known for high stability, Li2AlCoO4 represents a more exotic, metastable variant that incorporates aluminum into the lattice to potentially tune electrochemical properties and structural integrity.

Explore

Related Compounds

Other Layered Lithium Transition-Metal Oxides in the database.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

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