HfF4

Hafnium(IV) fluoride · Hafnium tetrafluoride

Hafnium(IV) fluoride is a stable, wide-gap insulating material primarily used in the production of high-performance optical coatings and fluoride-based glasses.

FHf
Crystal structure of HfF4
Ground-state structure · Materials Project
Overview

About Hafnium(IV) fluoride

Hafnium(IV) fluoride is a robust, thermodynamically stable inorganic compound characterized by its insulating electronic nature. Its wide band gap makes it a significant material for applications requiring transparency across a broad spectral range, particularly in high-performance optical systems.

Due to its structural stability and chemical resilience, this compound is frequently utilized in the development of specialized fluoride glasses and thin-film coatings. It serves as a critical component in advanced manufacturing processes where thermal and chemical durability are essential for long-term component reliability.

At a glance

Key Properties

Cross-validated computational properties for Hafnium(IV) fluoride, aggregated across 2 databases.

Band Gap

5.41 eV
Range across DFT structures

Energy Above Hull

0.000 eV/atom
Best (lowest) across sources

Stability

On hull (stable)
1 DFT source

Structures

49
2 databases, 15 space groups
Uses

Applications

Where Hafnium(IV) fluoride is used.

Optical coatingsFluoride glass productionThin-film depositionSpecialized optical components
Reference

Frequently Asked Questions

Common questions about Hafnium(IV) fluoride, answered from cross-validated data.

What is HfF4?

Hafnium(IV) fluoride is a stable, wide-gap insulating material primarily used in the production of high-performance optical coatings and fluoride-based glasses.

More questions
What is HfF4 used for?
Hafnium(IV) fluoride (HfF4) is used in optical coatings, fluoride glass production, thin-film deposition, and specialized optical components.
What is the band gap of HfF4?
Hafnium(IV) fluoride (HfF4) has a DFT-computed band gap of 5.41 eV across 49 reported structures.
Is HfF4 a metal, semiconductor, or insulator?
With a wide band gap up to 5.41 eV it is an insulator / wide-band-gap material.
Is HfF4 thermodynamically stable?
Yes — Hafnium(IV) fluoride (HfF4) sits on the convex hull (energy above hull 0 eV/atom), i.e. on hull (stable).
How many polymorphs of HfF4 are known?
49 structures of HfF4 are reported across 2 databases, spanning 15 distinct space groups.
What elements does HfF4 contain?
Hafnium(IV) fluoride (HfF4) contains F and Hf (2 elements).
Where does the data for HfF4 come from?
HfF4 data is cross-referenced from latticegraph.
Comparison

How It Compares

As a highly stable fluoride, HfF4 occupies a specialized niche in materials science, often serving as a preferred alternative to other metal fluorides in applications where high chemical inertness and specific refractive indices are required.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

Analyze HfF4 in the Lattice Graph platform

Polymorph comparison, confidence scoring, supply-chain risk, and patent monitoring — across 53 integrated data sources.

Explore the Platform →