GeO2

Germanium dioxide · Germania

Germanium dioxide is a stable, wide-gap insulating oxide widely utilized for its superior optical properties in fiber-optic and glass technologies.

GeO
Crystal structure of GeO2
Ground-state structure · Materials Project
Overview

About Germanium dioxide

Germanium dioxide is a thermodynamically stable oxide that functions as a wide-gap insulator. Its robust structural nature allows it to exist in various forms, making it a critical material in high-performance optical applications. Due to its significant data richness, it remains a heavily studied compound for material scientists focusing on dielectric properties. The material is essential for modern telecommunications, where its unique refractive index and chemical stability are leveraged to create high-quality optical components. Its ability to form stable glasses makes it a cornerstone in the production of specialized lenses and fiber-optic cables that require precise light transmission characteristics.

At a glance

Key Properties

Cross-validated computational properties for Germanium dioxide, aggregated across 3 databases.

Band Gap

0.79–3.28 eV
Range across DFT structures

Energy Above Hull

0.000 eV/atom
Best (lowest) across sources

Stability

On hull (stable)
2 DFT sources

Structures

261
3 databases, 34 space groups
Synthesis

Synthesis Routes

Literature-extracted synthesis procedures targeting GeO2.

Solid State
Procedure available · ceder_solid_state
Solid State
Procedure available · ceder_solid_state
Solid State
Procedure available · ceder_solid_state
Solid State
Procedure available · ceder_solid_state
Uses

Applications

Where Germanium dioxide is used.

Optical fiber manufacturingSpecialized glass productionInfrared opticsCatalysis
Intellectual Property

Patent Landscape

5 patents reference GeO2 or close compositional variants.

PatentTitleAssigneeGranted
8585797Method for preparing nanocrystalline germanium in GeO2 and freestanding germanium nanoparticles
4817695Electrical contact material of Ag, SnO.sub.2, GeO.sub.2 and In.sub.2 O.sub. 3
10553423Atomic layer deposition of GeO2
9171715Atomic layer deposition of GeO2
10811249Atomic layer deposition of GeO2
Reference

Frequently Asked Questions

Common questions about Germanium dioxide, answered from cross-validated data.

What is GeO2?

Germanium dioxide is a stable, wide-gap insulating oxide widely utilized for its superior optical properties in fiber-optic and glass technologies.

More questions
What is GeO2 used for?
Germanium dioxide (GeO2) is used in optical fiber manufacturing, specialized glass production, infrared optics, and catalysis.
What is the band gap of GeO2?
Germanium dioxide (GeO2) has a DFT-computed band gap of 0.79–3.28 eV across 261 reported structures.
Is GeO2 a metal, semiconductor, or insulator?
With a wide band gap up to 3.28 eV it is an insulator / wide-band-gap material.
Is GeO2 thermodynamically stable?
Yes — Germanium dioxide (GeO2) sits on the convex hull (energy above hull 0 eV/atom), i.e. on hull (stable).
How many polymorphs of GeO2 are known?
261 structures of GeO2 are reported across 3 databases, spanning 34 distinct space groups.
How is GeO2 synthesized?
Literature-reported routes for GeO2 include solid state (4 procedures documented).
What elements does GeO2 contain?
Germanium dioxide (GeO2) contains Ge and O (2 elements).
Where does the data for GeO2 come from?
GeO2 data is cross-referenced from latticegraph.
Comparison

How It Compares

As a primary oxide of germanium, this compound serves as the fundamental reference point for the material class, demonstrating exceptional thermodynamic stability compared to other germanium-based compounds.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

Analyze GeO2 in the Lattice Graph platform

Polymorph comparison, confidence scoring, supply-chain risk, and patent monitoring — across 53 integrated data sources.

Explore the Platform →