GeH4

Germane · Germanium tetrahydride

Germane is a stable, gaseous germanium hydride widely utilized as a chemical precursor for the production of semiconductor materials and thin films.

GeH
Crystal structure of GeH4
Ground-state structure · Materials Project
Overview

About Germane

Germane is a volatile inorganic hydride consisting of a central germanium atom bonded to four hydrogen atoms. As a thermodynamically stable compound, it serves as a critical gaseous source of high-purity germanium for advanced material synthesis. Its insulating electronic character makes it a specialized reagent in chemical vapor deposition rather than a functional electronic material itself. The compound is widely recognized for its role in the epitaxial growth of silicon-germanium alloys, which are essential for high-speed microelectronics. Its stability allows for precise control during the manufacturing of complex semiconductor architectures.

At a glance

Key Properties

Cross-validated computational properties for Germane, aggregated across 3 databases.

Band Gap

1.14–5.93 eV
Range across DFT structures

Energy Above Hull

0.000 eV/atom
Best (lowest) across sources

Stability

On hull (stable)
2 DFT sources

Structures

24
3 databases, 8 space groups
Uses

Applications

Where Germane is used.

Semiconductor manufacturingChemical vapor depositionEpitaxial growth of silicon-germanium alloysDoping of semiconductors
Reference

Frequently Asked Questions

Common questions about Germane, answered from cross-validated data.

What is GeH4?

Germane is a stable, gaseous germanium hydride widely utilized as a chemical precursor for the production of semiconductor materials and thin films.

More questions
What is GeH4 used for?
Germane (GeH4) is used in semiconductor manufacturing, chemical vapor deposition, epitaxial growth of silicon-germanium alloys, and doping of semiconductors.
What is the band gap of GeH4?
Germane (GeH4) has a DFT-computed band gap of 1.14–5.93 eV across 24 reported structures.
Is GeH4 a metal, semiconductor, or insulator?
With a wide band gap up to 5.93 eV it is an insulator / wide-band-gap material.
Is GeH4 thermodynamically stable?
Yes — Germane (GeH4) sits on the convex hull (energy above hull 0 eV/atom), i.e. on hull (stable).
How many polymorphs of GeH4 are known?
24 structures of GeH4 are reported across 3 databases, spanning 8 distinct space groups.
What elements does GeH4 contain?
Germane (GeH4) contains Ge and H (2 elements).
Where does the data for GeH4 come from?
GeH4 data is cross-referenced from latticegraph.
Reading

Related Research

Comparison

How It Compares

As a primary hydride in its chemical family, germane functions as the foundational germanium-based precursor for thin-film technology, representing the standard gaseous delivery method for incorporating germanium into solid-state devices.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

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