GeF2

Germanium difluoride · Germanium(II) fluoride

Germanium difluoride is a chemical compound composed of germanium and fluorine. It is primarily utilized as a precursor in chemical synthesis and materials science research for the deposition of germanium-containing thin films.

FGe
Crystal structure of GeF2 (orthorhombic, P212121 (No. 19))
Ground-state structure · Materials Project
Overview

Key Properties

Cross-validated computational properties for Germanium difluoride, aggregated across 3 databases.

Band Gap

4.06–4.14 eV
Range across DFT structures

Energy Above Hull

0.006 eV/atom
Best (lowest) across sources

Stability

Near hull (likely stable)
2 DFT sources

Structures

119
3 databases, 20 space groups
Crystallography

Reported Structures

Lowest-energy structures reported for GeF2, ranked by energy above hull.

Space GroupCrystal SystemBand Gap (eV)E above hull (eV/atom)E/atom (eV)Density (g/cm³)
P212121 (No. 19)orthorhombic4.060.0064-8.8623.88
Pnma (No. 62)orthorhombic4.140.0143-8.8543.88
Fmm2 (No. 42)Orthorhombic6.30
Fmm2 (No. 42)Orthorhombic5.15
Fmm2 (No. 42)Orthorhombic4.72
Cm (No. 8)Monoclinic5.74
Cm (No. 8)Monoclinic5.63
Cm (No. 8)Monoclinic5.60
Pm (No. 6)Monoclinic2.16
P1 (No. 1)Triclinic2.58
P1 (No. 1)Triclinic3.21
P3m1 (No. 156)Trigonal5.99
Uses

Applications

Where Germanium difluoride is used.

Chemical vapor depositionSemiconductor manufacturing researchSynthetic chemistry reagent
Reference

Frequently Asked Questions

Common questions about Germanium difluoride, answered from cross-validated data.

What is GeF2?

Germanium difluoride is a chemical compound composed of germanium and fluorine. It is primarily utilized as a precursor in chemical synthesis and materials science research for the deposition of germanium-containing thin films.

More questions
What is GeF2 used for?
Germanium difluoride (GeF2) is used in chemical vapor deposition, semiconductor manufacturing research, and synthetic chemistry reagent.
What is the band gap of GeF2?
Germanium difluoride (GeF2) has a DFT-computed band gap of 4.06–4.14 eV across 119 reported structures.
Is GeF2 a metal, semiconductor, or insulator?
With a wide band gap up to 4.14 eV it is an insulator / wide-band-gap material.
Is GeF2 thermodynamically stable?
Germanium difluoride (GeF2) has a lowest energy above hull of 0.006 eV/atom (near hull (likely stable)).
What is the crystal structure of GeF2?
The lowest-energy reported polymorph of Germanium difluoride (GeF2) is orthorhombic symmetry, space group P212121 (No. 19).
What is the density of GeF2?
The computed density of the ground-state structure of Germanium difluoride (GeF2) is 3.88 g/cm³.
How many polymorphs of GeF2 are known?
119 structures of GeF2 are reported across 3 databases, spanning 20 distinct space groups.
What elements does GeF2 contain?
Germanium difluoride (GeF2) contains F and Ge (2 elements).
Where does the data for GeF2 come from?
GeF2 data is cross-referenced from materials_project, mpaloe.
Data sources & attribution
  • materials_project — Data from the Materials Project. Cite: Jain et al., APL Materials 1, 011002 (2013).
  • mpaloe — Data from mpaloe.

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