GeCl4

Germanium tetrachloride · Germanium(IV) chloride

Germanium tetrachloride is a volatile, insulating liquid compound widely utilized as a chemical precursor for manufacturing optical fibers and semiconductor materials.

ClGe
Crystal structure of GeCl4
Ground-state structure · Materials Project
Overview

About Germanium tetrachloride

Germanium tetrachloride is a thermodynamically stable inorganic halide that functions as a wide-gap insulator. It is a highly volatile liquid at room temperature, making it a versatile reagent in chemical vapor deposition processes.

Due to its high purity and chemical reactivity, this compound serves as a fundamental building block in the semiconductor and telecommunications industries. It is essential for the synthesis of germanium-based materials and specialized glass products.

At a glance

Key Properties

Cross-validated computational properties for Germanium tetrachloride, aggregated across 4 databases.

Band Gap

4.15 eV
Range across DFT structures

Energy Above Hull

0.000 eV/atom
Best (lowest) across sources

Stability

On hull (stable)
2 DFT sources

Structures

19
4 databases, 10 space groups
Uses

Applications

Where Germanium tetrachloride is used.

Optical fiber manufacturingChemical vapor depositionSemiconductor dopingSynthesis of organogermanium compounds
Intellectual Property

Patent Landscape

2 patents reference GeCl4 or close compositional variants.

PatentTitleAssigneeGranted
8486360GeCl4 and/or SiCl4 recovery process from optical fibers or glassy residues and process for producing SiCl4 fro
7682593Process for the production of Ge by reduction of GeCl4 with liquid metal
Reference

Frequently Asked Questions

Common questions about Germanium tetrachloride, answered from cross-validated data.

What is GeCl4?

Germanium tetrachloride is a volatile, insulating liquid compound widely utilized as a chemical precursor for manufacturing optical fibers and semiconductor materials.

More questions
What is GeCl4 used for?
Germanium tetrachloride (GeCl4) is used in optical fiber manufacturing, chemical vapor deposition, semiconductor doping, and synthesis of organogermanium compounds.
What is the band gap of GeCl4?
Germanium tetrachloride (GeCl4) has a DFT-computed band gap of 4.15 eV across 19 reported structures.
Is GeCl4 a metal, semiconductor, or insulator?
With a wide band gap up to 4.15 eV it is an insulator / wide-band-gap material.
Is GeCl4 thermodynamically stable?
Yes — Germanium tetrachloride (GeCl4) sits on the convex hull (energy above hull 0 eV/atom), i.e. on hull (stable).
How many polymorphs of GeCl4 are known?
19 structures of GeCl4 are reported across 4 databases, spanning 10 distinct space groups.
What elements does GeCl4 contain?
Germanium tetrachloride (GeCl4) contains Cl and Ge (2 elements).
Where does the data for GeCl4 come from?
GeCl4 data is cross-referenced from latticegraph.
Comparison

How It Compares

As a primary germanium-based halide, this compound serves as a foundational reference point for the synthesis of high-purity materials, representing a stable and well-characterized chemical species within its class.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

Analyze GeCl4 in the Lattice Graph platform

Polymorph comparison, confidence scoring, supply-chain risk, and patent monitoring — across 53 integrated data sources.

Explore the Platform →