Ge

Germanium · Ge

Germanium is a stable, semiconducting chemical element widely utilized in the production of high-tech electronic and optical components.

Ge
Crystal structure of Ge (cubic, Fd-3m (No. 227))
Ground-state structure · Materials Project
Overview

About Germanium

Germanium is a fundamental semiconducting element that serves as a cornerstone of modern materials science. Its status as a thermodynamically stable phase ensures its reliability for complex fabrication processes, making it a highly researched material with an extensive library of structural data available to scientists.

Due to its unique electronic properties, this element is essential for advanced technologies requiring precise signal manipulation. It remains a primary choice for engineers developing high-speed electronics and infrared optics, where its consistent performance under various conditions is highly valued.

At a glance

Key Properties

Cross-validated computational properties for Germanium, aggregated across 6 databases.

Band Gap

0.25–1.04 eV
Range across DFT structures · ground state: narrow gap

Energy Above Hull

0.000 eV/atom
Best (lowest) across sources

Stability

Stable
4 DFT sources

Structures

98
6 databases, 15 space groups
Validation

Cross-Source DFT Agreement

How well independent DFT databases agree on the thermodynamics of Ge. Tight agreement means computed properties can be trusted without re-running calculations.

Agreement Score

1.00 / 1.00
Trust tier: high

Hull Spread

0.000 eV
EAH spread across sources

Sources Compared

3
jarvis, materials_project, oqmd

Space Group Consensus

Mixed (most: Fd-3m (No. 227))
Crystallography

Reported Structures

Lowest-energy structures reported for Ge, ranked by energy above hull.

Space GroupCrystal SystemBand Gap (eV)E above hull (eV/atom)E/atom (eV)Density (g/cm³)
P43212 (No. 96)tetragonal0.260.00000.138—
P43212 (No. 96)tetragonal0.250.00000.138—
Fmmm (No. 69)orthorhombic0.000.00000.249—
R-3 (No. 148)trigonal0.000.00000.139—
P63/mmc (No. 194)hexagonal0.000.00000.367—
P63/mmc (No. 194)hexagonal0.000.00000.274—
I41/amd (No. 141)tetragonal0.000.00000.244—
P63/mmc (No. 194)hexagonal0.000.00000.010—
I41/amd (No. 141)tetragonal0.000.00000.243—
Cmmm (No. 65)orthorhombic0.000.00000.260—
I41/amd (No. 141)tetragonal0.000.00000.244—
——0.000.00000.000—
Synthesis

Synthesis Routes

Literature-extracted synthesis procedures targeting Ge.

Solid State
Procedure available · ceder_solid_state
Uses

Applications

Where Germanium is used.

Infrared opticsFiber-optic systemsSemiconductor devicesSolar cellsPolymerization catalysts
Reference

Frequently Asked Questions

Common questions about Germanium, answered from cross-validated data.

What is Ge?

Germanium is a stable, semiconducting chemical element widely utilized in the production of high-tech electronic and optical components.

More questions
What is Ge used for?
Germanium (Ge) is used in infrared optics, fiber-optic systems, semiconductor devices, solar cells, and polymerization catalysts.
What is the band gap of Ge?
Germanium (Ge) has a DFT-computed band gap of 0.25–1.04 eV across 98 reported structures. Standard DFT underestimates band gaps, so the measured gap is typically larger.
Is Ge a metal, semiconductor, or insulator?
DFT predicts a band gap of up to 1.04 eV (a semiconductor). Measured gaps are typically larger.
Is Ge thermodynamically stable?
Yes — Germanium (Ge) sits on the convex hull (energy above hull 0 eV/atom), i.e. stable.
What is the crystal structure of Ge?
The reference structure of Germanium (Ge) is cubic symmetry, space group Fd-3m (No. 227).
What is the density of Ge?
The computed density of the ground-state structure of Germanium (Ge) is 5.28 g/cm³.
How many polymorphs of Ge are known?
98 structures of Ge are reported across 6 databases, spanning 15 distinct space groups.
How is Ge synthesized?
Literature-reported routes for Ge include solid state.
What elements does Ge contain?
Germanium (Ge) contains Ge (1 element).
Where does the data for Ge come from?
Ge data is cross-referenced from jarvis, oqmd, materials_project.
Comparison

How It Compares

As a foundational elemental semiconductor, germanium occupies a unique position in the periodic table, bridging the gap between lighter and heavier group-four elements. It is widely recognized for its distinct electronic behavior and structural robustness, serving as a benchmark material for the development of modern semiconductor physics.

Data sources & attribution
  • jarvis — Data from JARVIS (jarvis.nist.gov), NIST. Cite: Choudhary et al., npj Comp. Mater. 6, 173 (2020). (LicenseRef-US-Gov-PD)
  • oqmd — Data from the OQMD (oqmd.org). Cite: Saal et al., JOM 65, 1501 (2013); Kirklin et al., npj Comp. Mater. 1, 15010 (2015). (CC-BY-4.0)
  • materials_project — Data from the Materials Project (materialsproject.org). Cite: Jain et al., APL Materials 1, 011002 (2013). (CC-BY-4.0)

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