CsSnI3

Cesium tin triiodide · CsSnI3

CsSnI3 is a lead-free, semiconducting halide perovskite used as a sustainable material for photovoltaic and optoelectronic applications.

Crystal structure of CsSnI3
Ground-state structure · Materials Project
Overview

About Cesium tin triiodide

CsSnI3 is a prominent member of the halide perovskite family, characterized by its semiconducting electronic structure. As a lead-free alternative, it has garnered significant interest for its potential to mitigate the environmental concerns associated with traditional lead-based photovoltaics.

This compound is thermodynamically stable, sitting on the convex hull, which makes it a robust candidate for material research. Its structural versatility is evidenced by the numerous reported crystal structures, positioning it as a highly studied material for next-generation optoelectronic devices.

At a glance

Key Properties

Cross-validated computational properties for Cesium tin triiodide, aggregated across 4 databases.

Band Gap

0.45–2.06 eV
Range across DFT structures

Energy Above Hull

0.000 eV/atom
Best (lowest) across sources

Stability

On hull (stable)
2 DFT sources

Structures

18
4 databases, 4 space groups
Uses

Applications

Where Cesium tin triiodide is used.

Photovoltaic solar cellsOptoelectronic devicesSemiconductor research
Intellectual Property

Patent Landscape

3 patents reference CsSnI3 or close compositional variants.

PatentTitleAssigneeGranted
9196482Solution-based synthesis of CsSnI3
8679445Synthesis of CsSnI3 by temperature gradient solid-phase sintering method
9334443Synthesis of CsSnI3 by a solution based method
Reference

Frequently Asked Questions

Common questions about Cesium tin triiodide, answered from cross-validated data.

What is CsSnI3?

CsSnI3 is a lead-free, semiconducting halide perovskite used as a sustainable material for photovoltaic and optoelectronic applications.

More questions
What is CsSnI3 used for?
Cesium tin triiodide (CsSnI3) is used in photovoltaic solar cells, optoelectronic devices, and semiconductor research.
What is the band gap of CsSnI3?
Cesium tin triiodide (CsSnI3) has a DFT-computed band gap of 0.45–2.06 eV across 18 reported structures.
Is CsSnI3 a metal, semiconductor, or insulator?
With a band gap up to 2.06 eV it is a semiconductor.
Is CsSnI3 thermodynamically stable?
Yes — Cesium tin triiodide (CsSnI3) sits on the convex hull (energy above hull 0 eV/atom), i.e. on hull (stable).
How many polymorphs of CsSnI3 are known?
18 structures of CsSnI3 are reported across 4 databases, spanning 4 distinct space groups.
What elements does CsSnI3 contain?
Cesium tin triiodide (CsSnI3) contains Cs, I, and Sn (3 elements).
Where does the data for CsSnI3 come from?
CsSnI3 data is cross-referenced from latticegraph.
Comparison

How It Compares

Within the halide perovskite photovoltaics class.

Within the landscape of halide perovskites, CsSnI3 serves as a critical lead-free counterpart to materials like CsPbBr3 and CsI3Pb. While lead-based analogs are often favored for their high performance, CsSnI3 offers a more sustainable path forward, balancing structural stability with the electronic properties required for efficient light harvesting.

Explore

Related Compounds

Other Halide Perovskite Photovoltaics in the database.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

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