Cs2S

cesium sulfide

Cesium sulfide is a stable semiconducting compound formed from cesium and sulfur that is primarily used in specialized chemical synthesis and materials research.

CsS
Crystal structure of Cs2S
Ground-state structure · Materials Project
Overview

About cesium sulfide

Cesium sulfide is a binary inorganic compound composed of cesium and sulfur. As a thermodynamically stable material situated on the convex hull, it represents a well-defined chemical phase that maintains structural integrity under standard conditions.

This semiconducting material is of interest for its unique electronic properties and its role as a precursor in the synthesis of complex chalcogenide systems. Its stability makes it a reliable subject for fundamental studies in solid-state chemistry and materials research.

At a glance

Key Properties

Cross-validated computational properties for cesium sulfide, aggregated across 2 databases.

Band Gap

2.10 eV
Range across DFT structures

Energy Above Hull

0.000 eV/atom
Best (lowest) across sources

Stability

On hull (stable)
1 DFT source

Structures

47
2 databases, 7 space groups
Synthesis

Synthesis Routes

Literature-extracted synthesis procedures targeting Cs2S.

Solid State
Procedure available · ceder_solid_state
Solid State
Procedure available · ceder_solid_state
Solid State
Procedure available · ceder_solid_state
Uses

Applications

Where cesium sulfide is used.

Chemical synthesis precursorSolid-state researchMaterials science studies
Reference

Frequently Asked Questions

Common questions about cesium sulfide, answered from cross-validated data.

What is Cs2S?

Cesium sulfide is a stable semiconducting compound formed from cesium and sulfur that is primarily used in specialized chemical synthesis and materials research.

More questions
What is Cs2S used for?
cesium sulfide (Cs2S) is used in chemical synthesis precursor, solid-state research, and materials science studies.
What is the band gap of Cs2S?
cesium sulfide (Cs2S) has a DFT-computed band gap of 2.10 eV across 47 reported structures.
Is Cs2S a metal, semiconductor, or insulator?
With a band gap up to 2.10 eV it is a semiconductor.
Is Cs2S thermodynamically stable?
Yes — cesium sulfide (Cs2S) sits on the convex hull (energy above hull 0 eV/atom), i.e. on hull (stable).
How many polymorphs of Cs2S are known?
47 structures of Cs2S are reported across 2 databases, spanning 7 distinct space groups.
How is Cs2S synthesized?
Literature-reported routes for Cs2S include solid state (3 procedures documented).
What elements does Cs2S contain?
cesium sulfide (Cs2S) contains Cs and S (2 elements).
Where does the data for Cs2S come from?
Cs2S data is cross-referenced from latticegraph.
Comparison

How It Compares

As a binary sulfide of an alkali metal, cesium sulfide serves as a fundamental reference point for understanding the bonding and structural trends within the broader family of alkali metal chalcogenides.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

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