ClO

chlorine monoxide · chlorine radical

Chlorine monoxide is a reactive, unstable radical molecule that acts as a key intermediate in atmospheric ozone depletion processes.

ClO
Crystal structure of ClO
Ground-state structure · Materials Project
Overview

About chlorine monoxide

Chlorine monoxide is a reactive radical species composed of chlorine and oxygen. As a semiconducting molecule, it plays a critical role in atmospheric chemistry, particularly in the catalytic cycles that influence the ozone layer. Its electronic structure is defined by an unpaired electron, which drives its high reactivity and short-lived existence in natural environments.

Due to its position above the thermodynamic hull, this compound is inherently unstable and tends to participate rapidly in chemical reactions rather than existing as a stable bulk solid. Its presence is primarily observed in transient states, making it a subject of extensive study in environmental science and atmospheric modeling.

At a glance

Key Properties

Cross-validated computational properties for chlorine monoxide, aggregated across 3 databases.

Band Gap

1.69 eV
Range across DFT structures

Energy Above Hull

0.216 eV/atom
Best (lowest) across sources

Stability

Above hull
2 DFT sources

Structures

104
3 databases, 25 space groups
Uses

Applications

Where chlorine monoxide is used.

Atmospheric researchChemical kinetics studiesOzone depletion modeling
Reference

Frequently Asked Questions

Common questions about chlorine monoxide, answered from cross-validated data.

What is ClO?

Chlorine monoxide is a reactive, unstable radical molecule that acts as a key intermediate in atmospheric ozone depletion processes.

More questions
What is ClO used for?
chlorine monoxide (ClO) is used in atmospheric research, chemical kinetics studies, and ozone depletion modeling.
What is the band gap of ClO?
chlorine monoxide (ClO) has a DFT-computed band gap of 1.69 eV across 104 reported structures.
Is ClO a metal, semiconductor, or insulator?
With a band gap up to 1.69 eV it is a semiconductor.
Is ClO thermodynamically stable?
chlorine monoxide (ClO) has a lowest energy above hull of 0.216 eV/atom (above hull).
How many polymorphs of ClO are known?
104 structures of ClO are reported across 3 databases, spanning 25 distinct space groups.
What elements does ClO contain?
chlorine monoxide (ClO) contains Cl and O (2 elements).
Where does the data for ClO come from?
ClO data is cross-referenced from latticegraph.
Comparison

How It Compares

As a highly reactive radical, chlorine monoxide functions as a distinct chemical intermediate rather than a traditional structural material. Unlike stable, bulk inorganic compounds, it is defined by its fleeting existence and its pivotal role in gas-phase atmospheric kinetics.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

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