CF4

Carbon tetrafluoride · Tetrafluoromethane, R-14, PFC-14

Carbon tetrafluoride is a stable, insulating fluorocarbon gas primarily used as an etchant and refrigerant in industrial and electronic applications.

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Crystal structure of CF4
Ground-state structure · Materials Project
Overview

About Carbon tetrafluoride

Carbon tetrafluoride is a robust, chemically inert compound characterized by its wide-band-gap insulating electronic structure. As a thermodynamically stable molecule, it maintains structural integrity under a variety of demanding environmental conditions, making it a reliable component in industrial gas applications.

Its unique chemical properties are leveraged extensively in high-precision manufacturing, particularly where electrical insulation and plasma stability are required. The compound serves as a critical agent in the microelectronics industry, facilitating precise material removal and surface modification during chip fabrication.

At a glance

Key Properties

Cross-validated computational properties for Carbon tetrafluoride, aggregated across 3 databases.

Band Gap

9.07 eV
Range across DFT structures

Energy Above Hull

0.000 eV/atom
Best (lowest) across sources

Stability

On hull (stable)
2 DFT sources

Structures

3
3 databases, 1 space group
Uses

Applications

Where Carbon tetrafluoride is used.

Plasma etching in semiconductor manufacturingRefrigerantDielectric gasChemical vapor deposition
Intellectual Property

Patent Landscape

2 patents reference CF4 or close compositional variants.

PatentTitleAssigneeGranted
9318319Radical-enhanced atomic layer deposition using CF4 to enhance oxygen radical generation
6086777Tantalum barrier metal removal by using CF.sub.4 /o.sub.2 plasma dry etch
Reference

Frequently Asked Questions

Common questions about Carbon tetrafluoride, answered from cross-validated data.

What is CF4?

Carbon tetrafluoride is a stable, insulating fluorocarbon gas primarily used as an etchant and refrigerant in industrial and electronic applications.

More questions
What is CF4 used for?
Carbon tetrafluoride (CF4) is used in plasma etching in semiconductor manufacturing, refrigerant, dielectric gas, and chemical vapor deposition.
What is the band gap of CF4?
Carbon tetrafluoride (CF4) has a DFT-computed band gap of 9.07 eV across 3 reported structures.
Is CF4 a metal, semiconductor, or insulator?
With a wide band gap up to 9.07 eV it is an insulator / wide-band-gap material.
Is CF4 thermodynamically stable?
Yes — Carbon tetrafluoride (CF4) sits on the convex hull (energy above hull 0 eV/atom), i.e. on hull (stable).
How many polymorphs of CF4 are known?
3 structures of CF4 are reported across 3 databases, spanning 1 distinct space group.
What elements does CF4 contain?
Carbon tetrafluoride (CF4) contains C and F (2 elements).
Where does the data for CF4 come from?
CF4 data is cross-referenced from latticegraph.
Comparison

How It Compares

As a foundational fluorocarbon, this compound represents the simplest perfluorinated alkane, serving as a benchmark for stability and inertness within the broader class of fluorinated gases. Unlike more complex or reactive fluorocarbons, its structural simplicity and thermodynamic favorability make it a primary choice for applications requiring high dielectric strength and chemical resistance.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

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