BiPd

BiPd is a thermodynamically stable, metallic intermetallic compound of bismuth and palladium used in catalytic research.

Crystal structure of BiPd
Ground-state structure · Materials Project
Overview

About BiPd

BiPd is a metallic intermetallic compound composed of bismuth and palladium. As a member of the platinum-group alloy catalyst family, it is recognized for its thermodynamic stability, sitting firmly on the convex hull, which indicates a robust structural configuration under standard conditions. Its electronic character is defined by its metallic nature, lacking a band gap, which facilitates efficient electron transport in catalytic environments. The compound is highly structurally diverse, with numerous reported configurations across multiple databases, making it a significant subject for materials scientists studying phase behavior and catalytic surface activity. Its utility stems from the synergistic combination of a heavy post-transition metal and a noble platinum-group element, which often results in unique electronic environments at the atomic scale. This makes BiPd a compelling candidate for applications requiring precise control over surface-mediated chemical reactions.

At a glance

Key Properties

Cross-validated computational properties for BiPd, aggregated across 4 databases.

Band Gap

Metallic / not reported

Energy Above Hull

0.000 eV/atom
Best (lowest) across sources

Stability

On hull (stable)
2 DFT sources

Structures

47
4 databases, 14 space groups
Validation

Cross-Source DFT Agreement

How well independent DFT databases agree on the thermodynamics of BiPd. Tight agreement means computed properties can be trusted without re-running calculations.

Agreement Score

1.00 / 1.00
Trust tier: medium

Hull Spread

0.000 eV
EAH spread across sources

Sources Compared

2
jarvis, materials_project

Space Group Consensus

All match
Uses

Applications

Where BiPd is used.

Heterogeneous catalysisElectrocatalysisSurface science research
Reference

Frequently Asked Questions

Common questions about BiPd, answered from cross-validated data.

What is BiPd?

BiPd is a thermodynamically stable, metallic intermetallic compound of bismuth and palladium used in catalytic research.

More questions
What is BiPd used for?
BiPd is used in heterogeneous catalysis, electrocatalysis, and surface science research.
What is the band gap of BiPd?
BiPd is computed to be metallic (no band gap) in the reported DFT structures.
Is BiPd a metal, semiconductor, or insulator?
Computed band structures report no gap, so it is metallic.
Is BiPd thermodynamically stable?
Yes — BiPd sits on the convex hull (energy above hull 0 eV/atom), i.e. on hull (stable).
How many polymorphs of BiPd are known?
47 structures of BiPd are reported across 4 databases, spanning 14 distinct space groups.
What elements does BiPd contain?
BiPd contains Bi and Pd (2 elements).
Where does the data for BiPd come from?
BiPd data is cross-referenced from latticegraph.
Comparison

How It Compares

Within the platinum-group alloy catalysts class.

Within the class of platinum-group alloy catalysts, BiPd distinguishes itself through its high structural versatility compared to more rigid or simpler binary systems like BaPd or GeRu. While many members of this group, such as As2Pt or IrSe2, are frequently investigated for their specific coordination geometries, BiPd stands out as a thermodynamically stable phase that offers a distinct balance of metallic conductivity and chemical reactivity, providing a different catalytic pathway than the ruthenium or iridium-based counterparts.

Explore

Related Compounds

Other Platinum-Group Alloy Catalysts in the database.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

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