AsF5

Arsenic pentafluoride · Arsenic(V) fluoride

Arsenic pentafluoride is a stable, colorless gas that functions as a powerful fluorinating agent and a chemical dopant.

AsF
Crystal structure of AsF5
Ground-state structure · Materials Project
Overview

About Arsenic pentafluoride

Arsenic pentafluoride is a highly reactive inorganic compound that exists as a thermodynamically stable species. Its electronic character as a wide-band-gap insulator defines its behavior in chemical synthesis and industrial processes where strong Lewis acidity is required.

Due to its unique structural properties and high stability, this compound serves as a critical reagent in the production of advanced materials. It is frequently utilized in chemical research to facilitate complex fluorination reactions and as a dopant to modify the electrical properties of synthetic polymers.

At a glance

Key Properties

Cross-validated computational properties for Arsenic pentafluoride, aggregated across 4 databases.

Band Gap

4.60 eV
Range across DFT structures

Energy Above Hull

0.000 eV/atom
Best (lowest) across sources

Stability

On hull (stable)
3 DFT sources

Structures

20
4 databases, 7 space groups
Uses

Applications

Where Arsenic pentafluoride is used.

Fluorinating agentDopant for conductive polymersLewis acid catalystChemical synthesis
Intellectual Property

Patent Landscape

2 patents reference AsF5 or close compositional variants.

PatentTitleAssigneeGranted
8815058Extractive distillation of AsF5 and PF5 using HF
4617143Oxidizing polymerization with AsF.sub.5
Reference

Frequently Asked Questions

Common questions about Arsenic pentafluoride, answered from cross-validated data.

What is AsF5?

Arsenic pentafluoride is a stable, colorless gas that functions as a powerful fluorinating agent and a chemical dopant.

More questions
What is AsF5 used for?
Arsenic pentafluoride (AsF5) is used in fluorinating agent, dopant for conductive polymers, lewis acid catalyst, and chemical synthesis.
What is the band gap of AsF5?
Arsenic pentafluoride (AsF5) has a DFT-computed band gap of 4.60 eV across 20 reported structures.
Is AsF5 a metal, semiconductor, or insulator?
With a wide band gap up to 4.60 eV it is an insulator / wide-band-gap material.
Is AsF5 thermodynamically stable?
Yes — Arsenic pentafluoride (AsF5) sits on the convex hull (energy above hull 0 eV/atom), i.e. on hull (stable).
How many polymorphs of AsF5 are known?
20 structures of AsF5 are reported across 4 databases, spanning 7 distinct space groups.
What elements does AsF5 contain?
Arsenic pentafluoride (AsF5) contains As and F (2 elements).
Where does the data for AsF5 come from?
AsF5 data is cross-referenced from latticegraph.
Comparison

How It Compares

As a standalone member of the arsenic fluoride family, this compound is distinguished by its high thermodynamic stability and its role as a potent electron acceptor. Unlike lower-valent arsenic fluorides, it is primarily valued for its intense reactivity and its ability to act as a strong Lewis acid in various synthetic applications.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

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