AgO

Silver(I,III) oxide · Silver peroxide

AgO is a stable, semiconducting mixed-valence oxide of silver widely utilized for its high energy density in advanced battery technologies.

AgO
Crystal structure of AgO
Ground-state structure · Materials Project
Overview

About Silver(I,III) oxide

Silver(I,III) oxide is a distinct inorganic compound characterized by its mixed-valence state, where silver atoms occupy two different oxidation environments within the crystal lattice. As a thermodynamically stable material situated on the convex hull, it exhibits robust structural integrity that makes it a reliable candidate for electrochemical applications.

This semiconducting oxide is primarily recognized for its high energy density and efficient charge-transfer capabilities. Its ability to undergo specific reduction processes allows it to function effectively in demanding power storage environments where consistent performance and stability are required.

At a glance

Key Properties

Cross-validated computational properties for Silver(I,III) oxide, aggregated across 6 databases.

Band Gap

0.12–0.18 eV
Range across DFT structures

Energy Above Hull

0.000 eV/atom
Best (lowest) across sources

Stability

On hull (stable)
4 DFT sources

Structures

304
6 databases, 37 space groups
Validation

Cross-Source DFT Agreement

How well independent DFT databases agree on the thermodynamics of AgO. Tight agreement means computed properties can be trusted without re-running calculations.

Agreement Score

1.00 / 1.00
Trust tier: high

Hull Spread

0.000 eV
EAH spread across sources

Sources Compared

3
jarvis, materials_project, nomad

Space Group Consensus

All match
Synthesis

Synthesis Routes

Literature-extracted synthesis procedures targeting AgO.

Sol Gel
Procedure available · ceder_sol_gel
Sol Gel
Procedure available · ceder_sol_gel
Sol Gel
Procedure available · ceder_sol_gel
Sol Gel
Procedure available · ceder_sol_gel
Sol Gel
Procedure available · ceder_sol_gel
Sol Gel
Procedure available · ceder_sol_gel
Uses

Applications

Where Silver(I,III) oxide is used.

Primary silver-zinc batteriesHigh-energy density electrochemical cellsOxidizing agent in chemical synthesis
Intellectual Property

Patent Landscape

5 patents reference AgO or close compositional variants.

PatentTitleAssigneeGranted
4835077AgO cathode material
6001508AgO cathode battery
5389469AgO battery, and material
3953239Al-AgO primary battery
4056664Electrochemical cell having an AgO electrode discharging at an Ag.sub.2 O voltage level
Reference

Frequently Asked Questions

Common questions about Silver(I,III) oxide, answered from cross-validated data.

What is AgO?

AgO is a stable, semiconducting mixed-valence oxide of silver widely utilized for its high energy density in advanced battery technologies.

More questions
What is AgO used for?
Silver(I,III) oxide (AgO) is used in primary silver-zinc batteries, high-energy density electrochemical cells, and oxidizing agent in chemical synthesis.
What is the band gap of AgO?
Silver(I,III) oxide (AgO) has a DFT-computed band gap of 0.12–0.18 eV across 304 reported structures.
Is AgO a metal, semiconductor, or insulator?
With a band gap up to 0.18 eV it is a semiconductor.
Is AgO thermodynamically stable?
Yes — Silver(I,III) oxide (AgO) sits on the convex hull (energy above hull 0 eV/atom), i.e. on hull (stable).
How many polymorphs of AgO are known?
304 structures of AgO are reported across 6 databases, spanning 37 distinct space groups.
How is AgO synthesized?
Literature-reported routes for AgO include sol gel (10 procedures documented).
What elements does AgO contain?
Silver(I,III) oxide (AgO) contains Ag and O (2 elements).
Where does the data for AgO come from?
AgO data is cross-referenced from latticegraph.
Comparison

How It Compares

As a singular, highly studied compound in its category, AgO serves as a benchmark for silver-based oxides. Its status as a thermodynamically stable semiconductor distinguishes it from less stable or more transient metal oxide phases, positioning it as a primary choice for applications requiring high electrochemical reliability.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

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