Ag2O3

silver(III) oxide · silver sesquioxide

Silver(III) oxide is a semiconducting binary compound of silver and oxygen that is considered a promising candidate for synthesis due to its proximity to the thermodynamic stability hull.

AgO
Crystal structure of Ag2O3
Ground-state structure · Materials Project
Overview

About silver(III) oxide

Silver(III) oxide is a high-oxidation-state binary compound that functions as a semiconductor. Its position near the thermodynamic stability hull suggests it is a viable candidate for experimental synthesis and characterization within the broader family of silver-oxygen systems.

This material is significant for researchers exploring unconventional oxidation states in transition metal oxides. Due to its electronic character and structural complexity, it serves as a critical model for understanding the stability limits of silver-based compounds in various chemical environments.

At a glance

Key Properties

Cross-validated computational properties for silver(III) oxide, aggregated across 4 databases.

Band Gap

0.35 eV
Range across DFT structures

Energy Above Hull

0.019 eV/atom
Best (lowest) across sources

Stability

Near hull (likely stable)
3 DFT sources

Structures

57
4 databases, 14 space groups
Uses

Applications

Where silver(III) oxide is used.

Electrochemical researchAdvanced battery electrode studiesCatalysis research
Reference

Frequently Asked Questions

Common questions about silver(III) oxide, answered from cross-validated data.

What is Ag2O3?

Silver(III) oxide is a semiconducting binary compound of silver and oxygen that is considered a promising candidate for synthesis due to its proximity to the thermodynamic stability hull.

More questions
What is Ag2O3 used for?
silver(III) oxide (Ag2O3) is used in electrochemical research, advanced battery electrode studies, and catalysis research.
What is the band gap of Ag2O3?
silver(III) oxide (Ag2O3) has a DFT-computed band gap of 0.35 eV across 57 reported structures.
Is Ag2O3 a metal, semiconductor, or insulator?
With a band gap up to 0.35 eV it is a semiconductor.
Is Ag2O3 thermodynamically stable?
silver(III) oxide (Ag2O3) has a lowest energy above hull of 0.019 eV/atom (near hull (likely stable)).
How many polymorphs of Ag2O3 are known?
57 structures of Ag2O3 are reported across 4 databases, spanning 14 distinct space groups.
What elements does Ag2O3 contain?
silver(III) oxide (Ag2O3) contains Ag and O (2 elements).
Where does the data for Ag2O3 come from?
Ag2O3 data is cross-referenced from latticegraph.
Comparison

How It Compares

As a unique high-valent silver oxide, this compound occupies a specialized niche in materials science, representing a challenging target for synthesis compared to the more common, lower-oxidation-state silver oxides.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

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