O22V12

O22V12 is a metastable semiconducting vanadium oxide used in the research and development of electrochromic and refractory materials.

Crystal structure of O22V12
Ground-state structure · Materials Project
Overview

About O22V12

O22V12 is a semiconducting oxide composed of vanadium and oxygen that occupies a unique position within the refractory-metal oxide family. As a metastable phase, it represents a specialized configuration of vanadium that offers distinct structural properties compared to more common stoichiometric oxides.

This compound is of significant interest in materials science due to its electronic characteristics, which make it a subject of study for advanced electrochromic applications. Its ability to exist in multiple structural forms highlights the complex phase space of vanadium-based materials and their utility in functional device engineering.

At a glance

Key Properties

Cross-validated computational properties for O22V12, aggregated across 3 databases.

Band Gap

0.45–0.74 eV
Range across DFT structures

Energy Above Hull

0.039 eV/atom
Best (lowest) across sources

Stability

Metastable
2 DFT sources

Structures

6
3 databases, 2 space groups
Uses

Applications

Where O22V12 is used.

Electrochromic device researchAdvanced materials engineeringSemiconductor studies
Reference

Frequently Asked Questions

Common questions about O22V12, answered from cross-validated data.

What is O22V12?

O22V12 is a metastable semiconducting vanadium oxide used in the research and development of electrochromic and refractory materials.

More questions
What is O22V12 used for?
O22V12 is used in electrochromic device research, advanced materials engineering, and semiconductor studies.
What is the band gap of O22V12?
O22V12 has a DFT-computed band gap of 0.45–0.74 eV across 6 reported structures.
Is O22V12 a metal, semiconductor, or insulator?
With a band gap up to 0.74 eV it is a semiconductor.
Is O22V12 thermodynamically stable?
O22V12 has a lowest energy above hull of 0.039 eV/atom (metastable).
How many polymorphs of O22V12 are known?
6 structures of O22V12 are reported across 3 databases, spanning 2 distinct space groups.
What elements does O22V12 contain?
O22V12 contains O and V (2 elements).
Where does the data for O22V12 come from?
O22V12 data is cross-referenced from latticegraph.
Comparison

How It Compares

Within the electrochromic and refractory-metal oxides class.

Within the broader class of refractory-metal oxides, O22V12 is less common than the widely studied V2O5, which serves as a benchmark for vanadium-based electrochromic materials. While siblings like MoO3 and WO3 are frequently utilized for their robust performance in optical switching, O22V12 represents a more niche, metastable alternative that provides researchers with a different structural framework for exploring semiconducting behavior in metal-oxide systems.

Explore

Related Compounds

Other Electrochromic and Refractory-Metal Oxides in the database.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

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