V2O5

Vanadium pentoxide · Vanadic anhydride, Vanadium(V) oxide

Vanadium pentoxide is a stable, semiconducting metal oxide widely utilized as a catalyst and in electrochromic applications.

Crystal structure of V2O5
Ground-state structure · Materials Project
Overview

About Vanadium pentoxide

Vanadium pentoxide is a thermodynamically stable, semiconducting oxide that serves as a cornerstone in industrial inorganic chemistry. Its ability to undergo reversible structural changes makes it a primary candidate for advanced electrochromic technologies and energy storage systems.

Beyond its electronic utility, the compound is highly valued for its catalytic properties in oxidation reactions. With extensive structural data available, it remains one of the most thoroughly characterized transition metal oxides in its class.

At a glance

Key Properties

Cross-validated computational properties for Vanadium pentoxide, aggregated across 4 databases.

Band Gap

0.03–2.75 eV
Range across DFT structures

Energy Above Hull

0.000 eV/atom
Best (lowest) across sources

Stability

On hull (stable)
2 DFT sources

Structures

120
4 databases, 19 space groups
Synthesis

Synthesis Routes

Literature-extracted synthesis procedures targeting V2O5.

Solid State
Procedure available · ceder_solid_state
Solid State
Procedure available · ceder_solid_state
Sol Gel
Procedure available · ceder_sol_gel
Solid State
Procedure available · ceder_solid_state
Solid State
Procedure available · ceder_solid_state
Solid State
Procedure available · ceder_solid_state
Uses

Applications

Where Vanadium pentoxide is used.

Industrial catalysisElectrochromic devicesLithium-ion battery cathodesChemical manufacturingPigment production
Intellectual Property

Patent Landscape

6 patents reference V2O5 or close compositional variants.

PatentTitleAssigneeGranted
9911969V2O5—LiBO2, V2O5—NiO—LiBO2 glasses and their composites obtained by nitrogen doping and reduced graphite oxide
12269014V2C@V2O5/TiO2 composite photocatalyst, preparation method, and application thereof
9464005Dielectric ceramic composition comprising Bi2O3, ZnO, Nb2O5 and V2O5, dielectric ceramic, electronic device, a
9515310V2O5 electrodes with high power and energy densities
10479900VO2 and V2O5 nano- and micro-materials and processes of making and uses of same
8945715Low V2O5—content and V2O5—free porcelain enamels
Reference

Frequently Asked Questions

Common questions about Vanadium pentoxide, answered from cross-validated data.

What is V2O5?

Vanadium pentoxide is a stable, semiconducting metal oxide widely utilized as a catalyst and in electrochromic applications.

More questions
What is V2O5 used for?
Vanadium pentoxide (V2O5) is used in industrial catalysis, electrochromic devices, lithium-ion battery cathodes, chemical manufacturing, and pigment production.
What is the band gap of V2O5?
Vanadium pentoxide (V2O5) has a DFT-computed band gap of 0.03–2.75 eV across 120 reported structures.
Is V2O5 a metal, semiconductor, or insulator?
With a band gap up to 2.75 eV it is a semiconductor.
Is V2O5 thermodynamically stable?
Yes — Vanadium pentoxide (V2O5) sits on the convex hull (energy above hull 0 eV/atom), i.e. on hull (stable).
How many polymorphs of V2O5 are known?
120 structures of V2O5 are reported across 4 databases, spanning 19 distinct space groups.
How is V2O5 synthesized?
Literature-reported routes for V2O5 include solid state, sol gel (10 procedures documented).
What elements does V2O5 contain?
Vanadium pentoxide (V2O5) contains O and V (2 elements).
Where does the data for V2O5 come from?
V2O5 data is cross-referenced from latticegraph.
Comparison

How It Compares

Within the electrochromic and refractory-metal oxides class.

Within the family of refractory-metal oxides, V2O5 is distinguished by its versatile oxidation states compared to the more rigid MoO3 or WO3 systems. While siblings like Nb2O5 and MoO3 are frequently utilized for their dielectric or catalytic stability, V2O5 offers a unique balance of semiconducting behavior and structural flexibility that facilitates its use in dynamic applications.

Explore

Related Compounds

Other Electrochromic and Refractory-Metal Oxides in the database.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

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