NiO2F

Nickel dioxide fluoride is an inorganic compound that has been studied for its potential role in advanced electrochemical energy storage systems. It is primarily investigated as a cathode material due to its ability to facilitate ion transport and participate in redox reactions.

Overview

Key Properties

Cross-validated computational properties for NiO2F, aggregated across 3 databases.

Band Gap

0.68 eV
Range across DFT structures

Energy Above Hull

0.376 eV/atom
Best (lowest) across sources

Stability

Above hull
2 DFT sources

Structures

8
3 databases, 5 space groups
Crystallography

Reported Structures

Lowest-energy structures reported for NiO2F, ranked by energy above hull.

Space GroupCrystal SystemBand Gap (eV)E above hull (eV/atom)E/atom (eV)Density (g/cm³)
Pca21 (No. 29)orthorhombic0.680.3760-4.8173.28
Cm (No. 8)Monoclinic5.88
Cm (No. 8)Monoclinic4.08
Cm (No. 8)Monoclinic4.35
P63/mmc (No. 194)Hexagonal4.94
P1 (No. 1)
P-3m1 (No. 164)Trigonal6.50
P63/mmc (No. 194)Hexagonal4.47
Uses

Applications

Where NiO2F is used.

Battery researchElectrochemical energy storageSolid-state chemistry
Reference

Frequently Asked Questions

Common questions about NiO2F, answered from cross-validated data.

What is NiO2F?

Nickel dioxide fluoride is an inorganic compound that has been studied for its potential role in advanced electrochemical energy storage systems. It is primarily investigated as a cathode material due to its ability to facilitate ion transport and participate in redox reactions.

More questions
What is NiO2F used for?
NiO2F is used in battery research, electrochemical energy storage, and solid-state chemistry.
What is the band gap of NiO2F?
NiO2F has a DFT-computed band gap of 0.68 eV across 8 reported structures.
Is NiO2F a metal, semiconductor, or insulator?
With a band gap up to 0.68 eV it is a semiconductor.
Is NiO2F thermodynamically stable?
NiO2F has a lowest energy above hull of 0.376 eV/atom (above hull).
What is the crystal structure of NiO2F?
The lowest-energy reported polymorph of NiO2F is orthorhombic symmetry, space group Pca21 (No. 29).
What is the density of NiO2F?
The computed density of the ground-state structure of NiO2F is 3.28 g/cm³.
How many polymorphs of NiO2F are known?
8 structures of NiO2F are reported across 3 databases, spanning 5 distinct space groups.
What elements does NiO2F contain?
NiO2F contains F, Ni, and O (3 elements).
Where does the data for NiO2F come from?
NiO2F data is cross-referenced from materials_project, mpaloe, jarvis.
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Related Compounds

Other Oxide Oxygen-Evolution Catalysts in the database.

Data sources & attribution
  • materials_project — Data from the Materials Project. Cite: Jain et al., APL Materials 1, 011002 (2013).
  • mpaloe — Data from mpaloe.
  • jarvis — Data from JARVIS (NIST). Cite: Choudhary et al., npj Comp. Mater. 6, 173 (2020).

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