NiClO
NiClO is a semiconducting nickel-based oxychloride that serves as an experimental material in the study of oxygen-evolution catalysts.
About NiClO
NiClO is a semiconducting oxide material primarily studied for its potential role in oxygen-evolution catalysis. As a member of this specialized class, it represents a complex coordination environment involving nickel, chlorine, and oxygen, which influences its electrochemical behavior and catalytic activity. Due to its position above the thermodynamic stability hull, this compound is considered metastable, making it a subject of interest for researchers exploring unconventional synthesis routes and stabilization techniques. Its structural complexity is highlighted by multiple reported configurations, reflecting the diverse ways these elements can arrange at the atomic scale.
Key Properties
Cross-validated computational properties for NiClO, aggregated across 3 databases.
Band GapEnergy needed to move an electron from the valence band to the conduction band. Lower or zero values tend to behave more metallic; larger gaps are more insulating or semiconducting.
Energy Above HullThermodynamic distance from the most stable set of competing phases. 0 eV/atom is on the convex hull; small positive values may still be experimentally accessible.
StabilityA plain-language summary of the best reported energy-above-hull result. It reflects whether the lowest-energy structure is on, near, or far from the stability hull.
StructuresCount of reported calculated crystal structures for this formula, including alternate polymorphs, source databases, and observed space groups.
Applications
Where NiClO is used.
Frequently Asked Questions
Common questions about NiClO, answered from cross-validated data.
What is NiClO?
NiClO is a semiconducting nickel-based oxychloride that serves as an experimental material in the study of oxygen-evolution catalysts.
What is NiClO used for?
What is the band gap of NiClO?
Is NiClO a metal, semiconductor, or insulator?
Is NiClO thermodynamically stable?
How many polymorphs of NiClO are known?
What elements does NiClO contain?
Where does the data for NiClO come from?
How It Compares
Within the oxide oxygen-evolution catalysts class.
Unlike the highly stable and widely utilized NiO or the layered lithium-based intercalation materials like LiCoO2 and LiNiO2, NiClO occupies a more precarious thermodynamic state. While perovskite-structured oxides such as LaNiO3 and LaMnO3 are often favored for their robust catalytic performance and structural integrity, NiClO offers a distinct chemical environment that challenges standard synthesis paradigms within the oxygen-evolution catalyst family.
Related Compounds
Other Oxide Oxygen-Evolution Catalysts in the database.
Data sources & attribution
- latticegraph — Lattice Graph Materials Intelligence Platform
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