Li6Mn5SbO12

Li6Mn5SbO12 is a metastable semiconducting oxide containing lithium, manganese, antimony, and oxygen that is primarily studied for its potential in advanced electrochemical energy storage applications.

Crystal structure of Li6Mn5SbO12
Ground-state structure · Materials Project
Overview

About Li6Mn5SbO12

Li6Mn5SbO12 is a complex layered lithium transition-metal oxide characterized by its semiconducting electronic nature. As a metastable phase, it represents a specialized configuration within the broader family of lithium-based oxides, offering unique structural arrangements for ion mobility and storage investigations. Its synthesis is of significant interest for researchers aiming to optimize electrode performance through precise elemental substitution.

This material serves as a critical subject for fundamental studies into the stability and electrochemical behavior of lithium-rich oxide frameworks. By incorporating antimony into the manganese-oxygen lattice, it provides a distinct chemical environment that differentiates it from conventional cathode materials, contributing to the ongoing development of next-generation energy storage solutions.

At a glance

Key Properties

Cross-validated computational properties for Li6Mn5SbO12, aggregated across 3 databases.

Band Gap

0.15–0.72 eV
Range across DFT structures

Energy Above Hull

0.040 eV/atom
Best (lowest) across sources

Stability

Metastable
2 DFT sources

Structures

8
3 databases, 3 space groups
Uses

Applications

Where Li6Mn5SbO12 is used.

Lithium-ion battery researchCathode material investigationSolid-state ionics
Reference

Frequently Asked Questions

Common questions about Li6Mn5SbO12, answered from cross-validated data.

What is Li6Mn5SbO12?

Li6Mn5SbO12 is a metastable semiconducting oxide containing lithium, manganese, antimony, and oxygen that is primarily studied for its potential in advanced electrochemical energy storage applications.

More questions
What is Li6Mn5SbO12 used for?
Li6Mn5SbO12 is used in lithium-ion battery research, cathode material investigation, and solid-state ionics.
What is the band gap of Li6Mn5SbO12?
Li6Mn5SbO12 has a DFT-computed band gap of 0.15–0.72 eV across 8 reported structures.
Is Li6Mn5SbO12 a metal, semiconductor, or insulator?
With a band gap up to 0.72 eV it is a semiconductor.
Is Li6Mn5SbO12 thermodynamically stable?
Li6Mn5SbO12 has a lowest energy above hull of 0.040 eV/atom (metastable).
How many polymorphs of Li6Mn5SbO12 are known?
8 structures of Li6Mn5SbO12 are reported across 3 databases, spanning 3 distinct space groups.
What elements does Li6Mn5SbO12 contain?
Li6Mn5SbO12 contains Li, Mn, O, and Sb (4 elements).
Where does the data for Li6Mn5SbO12 come from?
Li6Mn5SbO12 data is cross-referenced from latticegraph.
Comparison

How It Compares

Within the layered lithium transition-metal oxides class.

Within the diverse class of layered lithium transition-metal oxides, Li6Mn5SbO12 occupies a niche position compared to widely utilized industry standards like LiCoO2 and LiNiO2. While those materials are typically favored for their robust stability and established cycling performance, Li6Mn5SbO12 is a metastable variant that offers a unique structural alternative to the more common LiMn2O4 or Li2MnO3, providing researchers with a distinct platform to explore the effects of heavy-element doping on lithium-ion diffusion pathways.

Explore

Related Compounds

Other Layered Lithium Transition-Metal Oxides in the database.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

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